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Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′]
In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784659/ https://www.ncbi.nlm.nih.gov/pubmed/33520271 http://dx.doi.org/10.1107/S2056989020014322 |
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author | Fwu Ming, Shen Shie Fu, Lush |
author_facet | Fwu Ming, Shen Shie Fu, Lush |
author_sort | Fwu Ming, Shen |
collection | PubMed |
description | In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The 1,2-bis(pyridin-4-yl)ethane unit bridges two Zn(II) cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π interactions and π–π interactions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component. |
format | Online Article Text |
id | pubmed-7784659 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-77846592021-01-29 Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′] Fwu Ming, Shen Shie Fu, Lush Acta Crystallogr E Crystallogr Commun Research Communications In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The 1,2-bis(pyridin-4-yl)ethane unit bridges two Zn(II) cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π interactions and π–π interactions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component. International Union of Crystallography 2020-11-24 /pmc/articles/PMC7784659/ /pubmed/33520271 http://dx.doi.org/10.1107/S2056989020014322 Text en © Fwu Ming and Shie Fu 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Fwu Ming, Shen Shie Fu, Lush Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′] |
title | Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2)
O
(1),O
(2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′] |
title_full | Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2)
O
(1),O
(2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′] |
title_fullStr | Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2)
O
(1),O
(2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′] |
title_full_unstemmed | Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2)
O
(1),O
(2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′] |
title_short | Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2)
O
(1),O
(2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′] |
title_sort | crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2)
o
(1),o
(2)]zinc(ii)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2)
n:n′] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784659/ https://www.ncbi.nlm.nih.gov/pubmed/33520271 http://dx.doi.org/10.1107/S2056989020014322 |
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