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Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]

In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis­(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy­droxy(phen­yl)acetate] anions in a slightly distorted octa­hedral coordination geometry. The...

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Autores principales: Fwu Ming, Shen, Shie Fu, Lush
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784659/
https://www.ncbi.nlm.nih.gov/pubmed/33520271
http://dx.doi.org/10.1107/S2056989020014322
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author Fwu Ming, Shen
Shie Fu, Lush
author_facet Fwu Ming, Shen
Shie Fu, Lush
author_sort Fwu Ming, Shen
collection PubMed
description In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis­(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy­droxy(phen­yl)acetate] anions in a slightly distorted octa­hedral coordination geometry. The 1,2-bis­(pyridin-4-yl)ethane unit bridges two Zn(II) cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π inter­actions and π–π inter­actions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis­(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis­(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component.
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spelling pubmed-77846592021-01-29 Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] Fwu Ming, Shen Shie Fu, Lush Acta Crystallogr E Crystallogr Commun Research Communications In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis­(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy­droxy(phen­yl)acetate] anions in a slightly distorted octa­hedral coordination geometry. The 1,2-bis­(pyridin-4-yl)ethane unit bridges two Zn(II) cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π inter­actions and π–π inter­actions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis­(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis­(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component. International Union of Crystallography 2020-11-24 /pmc/articles/PMC7784659/ /pubmed/33520271 http://dx.doi.org/10.1107/S2056989020014322 Text en © Fwu Ming and Shie Fu 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Fwu Ming, Shen
Shie Fu, Lush
Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]
title Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]
title_full Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]
title_fullStr Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]
title_full_unstemmed Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]
title_short Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]
title_sort crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) o (1),o (2)]zinc(ii)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) n:n′]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784659/
https://www.ncbi.nlm.nih.gov/pubmed/33520271
http://dx.doi.org/10.1107/S2056989020014322
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