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Characterization and Biodegradability of Rice Husk-Filled Polymer Composites

The fabrication of affordable biodegradable plastics remains a challenging issue for both the scientific community and industries as mechanical properties and biodegradability improve at the expense of the high cost of the material. Hence, the present work deals with fabrication and characterization...

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Autores principales: Yap, Saw Yin, Sreekantan, Srimala, Hassan, Mohd, Sudesh, Kumar, Ong, Ming Thong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795183/
https://www.ncbi.nlm.nih.gov/pubmed/33383797
http://dx.doi.org/10.3390/polym13010104
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author Yap, Saw Yin
Sreekantan, Srimala
Hassan, Mohd
Sudesh, Kumar
Ong, Ming Thong
author_facet Yap, Saw Yin
Sreekantan, Srimala
Hassan, Mohd
Sudesh, Kumar
Ong, Ming Thong
author_sort Yap, Saw Yin
collection PubMed
description The fabrication of affordable biodegradable plastics remains a challenging issue for both the scientific community and industries as mechanical properties and biodegradability improve at the expense of the high cost of the material. Hence, the present work deals with fabrication and characterization of biodegradable polymer with 40% rice husk waste filler and 60% polymer-containing mixture of polybutylene succinate (PBS) and poly butylenes adipate-Co-terephthalate (PBAT) to achieve good mechanical properties, 92% biodegradation in six months, and competitive pricing. The challenge in incorporating high amounts of hydrophilic nature filler material into hydrophobic PBS/PBAT was addressed by adding plasticizers such as glycerol and calcium stearate. The compatibilizers such as maleic anhydride (MA) and dicumyl peroxide (DCP) was used to improve the miscibility between hydrophobic PBS/PBAT and hydrophilic filler material. The component with the formulation of 24:36:40 (PBS/PBAT/TPRH) possessed the tensile strength of 14.27 MPa, modulus of 200.43 MPa, and elongation at break of 12.99%, which was suitable for the production of molded products such as a tray, lunch box, and straw. The obtained composite polymer achieved 92% mass loss after six months of soil burial test confirming its biodegradability.
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spelling pubmed-77951832021-01-10 Characterization and Biodegradability of Rice Husk-Filled Polymer Composites Yap, Saw Yin Sreekantan, Srimala Hassan, Mohd Sudesh, Kumar Ong, Ming Thong Polymers (Basel) Article The fabrication of affordable biodegradable plastics remains a challenging issue for both the scientific community and industries as mechanical properties and biodegradability improve at the expense of the high cost of the material. Hence, the present work deals with fabrication and characterization of biodegradable polymer with 40% rice husk waste filler and 60% polymer-containing mixture of polybutylene succinate (PBS) and poly butylenes adipate-Co-terephthalate (PBAT) to achieve good mechanical properties, 92% biodegradation in six months, and competitive pricing. The challenge in incorporating high amounts of hydrophilic nature filler material into hydrophobic PBS/PBAT was addressed by adding plasticizers such as glycerol and calcium stearate. The compatibilizers such as maleic anhydride (MA) and dicumyl peroxide (DCP) was used to improve the miscibility between hydrophobic PBS/PBAT and hydrophilic filler material. The component with the formulation of 24:36:40 (PBS/PBAT/TPRH) possessed the tensile strength of 14.27 MPa, modulus of 200.43 MPa, and elongation at break of 12.99%, which was suitable for the production of molded products such as a tray, lunch box, and straw. The obtained composite polymer achieved 92% mass loss after six months of soil burial test confirming its biodegradability. MDPI 2020-12-29 /pmc/articles/PMC7795183/ /pubmed/33383797 http://dx.doi.org/10.3390/polym13010104 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yap, Saw Yin
Sreekantan, Srimala
Hassan, Mohd
Sudesh, Kumar
Ong, Ming Thong
Characterization and Biodegradability of Rice Husk-Filled Polymer Composites
title Characterization and Biodegradability of Rice Husk-Filled Polymer Composites
title_full Characterization and Biodegradability of Rice Husk-Filled Polymer Composites
title_fullStr Characterization and Biodegradability of Rice Husk-Filled Polymer Composites
title_full_unstemmed Characterization and Biodegradability of Rice Husk-Filled Polymer Composites
title_short Characterization and Biodegradability of Rice Husk-Filled Polymer Composites
title_sort characterization and biodegradability of rice husk-filled polymer composites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795183/
https://www.ncbi.nlm.nih.gov/pubmed/33383797
http://dx.doi.org/10.3390/polym13010104
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