Cargando…

Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent

In the cement industry, SO(2) and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yali, Han, Xiaoning, Chen, Meina, Cui, Suping, Ma, Xiaoyu, Hao, Liwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795989/
https://www.ncbi.nlm.nih.gov/pubmed/33375696
http://dx.doi.org/10.3390/ma14010068
_version_ 1783634574990901248
author Wang, Yali
Han, Xiaoning
Chen, Meina
Cui, Suping
Ma, Xiaoyu
Hao, Liwei
author_facet Wang, Yali
Han, Xiaoning
Chen, Meina
Cui, Suping
Ma, Xiaoyu
Hao, Liwei
author_sort Wang, Yali
collection PubMed
description In the cement industry, SO(2) and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In this paper, rice husk ash and carbide slag were compounded and modified to prepare modified rice husk ash-carbide slag composite absorbent, and its desulfurization and denitrification performance and mechanism were studied. The results showed that the NO conversion and SO(2) conversion of the modified rice husk ash-carbide slag composite absorbent increased by 44% and 2%, respectively, at 700 °C. Fibrous calcium silicate and calcium silicoaluminate hydrates were formed during the hydration process, which made the specific surface area of the absorbent larger and provided more reactive sites. The hydration process increases the content of oxygen-containing functional groups, decreases the hydroxyl/ether C–O functional groups, and increases the content of carboxyl–COO functional groups are conducive to the denitrification reaction.
format Online
Article
Text
id pubmed-7795989
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-77959892021-01-10 Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent Wang, Yali Han, Xiaoning Chen, Meina Cui, Suping Ma, Xiaoyu Hao, Liwei Materials (Basel) Article In the cement industry, SO(2) and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In this paper, rice husk ash and carbide slag were compounded and modified to prepare modified rice husk ash-carbide slag composite absorbent, and its desulfurization and denitrification performance and mechanism were studied. The results showed that the NO conversion and SO(2) conversion of the modified rice husk ash-carbide slag composite absorbent increased by 44% and 2%, respectively, at 700 °C. Fibrous calcium silicate and calcium silicoaluminate hydrates were formed during the hydration process, which made the specific surface area of the absorbent larger and provided more reactive sites. The hydration process increases the content of oxygen-containing functional groups, decreases the hydroxyl/ether C–O functional groups, and increases the content of carboxyl–COO functional groups are conducive to the denitrification reaction. MDPI 2020-12-25 /pmc/articles/PMC7795989/ /pubmed/33375696 http://dx.doi.org/10.3390/ma14010068 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wang, Yali
Han, Xiaoning
Chen, Meina
Cui, Suping
Ma, Xiaoyu
Hao, Liwei
Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
title Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
title_full Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
title_fullStr Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
title_full_unstemmed Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
title_short Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
title_sort desulfurization and denitrification performance of modified rice husk ash-carbide slag absorbent
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795989/
https://www.ncbi.nlm.nih.gov/pubmed/33375696
http://dx.doi.org/10.3390/ma14010068
work_keys_str_mv AT wangyali desulfurizationanddenitrificationperformanceofmodifiedricehuskashcarbideslagabsorbent
AT hanxiaoning desulfurizationanddenitrificationperformanceofmodifiedricehuskashcarbideslagabsorbent
AT chenmeina desulfurizationanddenitrificationperformanceofmodifiedricehuskashcarbideslagabsorbent
AT cuisuping desulfurizationanddenitrificationperformanceofmodifiedricehuskashcarbideslagabsorbent
AT maxiaoyu desulfurizationanddenitrificationperformanceofmodifiedricehuskashcarbideslagabsorbent
AT haoliwei desulfurizationanddenitrificationperformanceofmodifiedricehuskashcarbideslagabsorbent