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Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent
In the cement industry, SO(2) and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795989/ https://www.ncbi.nlm.nih.gov/pubmed/33375696 http://dx.doi.org/10.3390/ma14010068 |
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author | Wang, Yali Han, Xiaoning Chen, Meina Cui, Suping Ma, Xiaoyu Hao, Liwei |
author_facet | Wang, Yali Han, Xiaoning Chen, Meina Cui, Suping Ma, Xiaoyu Hao, Liwei |
author_sort | Wang, Yali |
collection | PubMed |
description | In the cement industry, SO(2) and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In this paper, rice husk ash and carbide slag were compounded and modified to prepare modified rice husk ash-carbide slag composite absorbent, and its desulfurization and denitrification performance and mechanism were studied. The results showed that the NO conversion and SO(2) conversion of the modified rice husk ash-carbide slag composite absorbent increased by 44% and 2%, respectively, at 700 °C. Fibrous calcium silicate and calcium silicoaluminate hydrates were formed during the hydration process, which made the specific surface area of the absorbent larger and provided more reactive sites. The hydration process increases the content of oxygen-containing functional groups, decreases the hydroxyl/ether C–O functional groups, and increases the content of carboxyl–COO functional groups are conducive to the denitrification reaction. |
format | Online Article Text |
id | pubmed-7795989 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-77959892021-01-10 Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent Wang, Yali Han, Xiaoning Chen, Meina Cui, Suping Ma, Xiaoyu Hao, Liwei Materials (Basel) Article In the cement industry, SO(2) and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In this paper, rice husk ash and carbide slag were compounded and modified to prepare modified rice husk ash-carbide slag composite absorbent, and its desulfurization and denitrification performance and mechanism were studied. The results showed that the NO conversion and SO(2) conversion of the modified rice husk ash-carbide slag composite absorbent increased by 44% and 2%, respectively, at 700 °C. Fibrous calcium silicate and calcium silicoaluminate hydrates were formed during the hydration process, which made the specific surface area of the absorbent larger and provided more reactive sites. The hydration process increases the content of oxygen-containing functional groups, decreases the hydroxyl/ether C–O functional groups, and increases the content of carboxyl–COO functional groups are conducive to the denitrification reaction. MDPI 2020-12-25 /pmc/articles/PMC7795989/ /pubmed/33375696 http://dx.doi.org/10.3390/ma14010068 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Wang, Yali Han, Xiaoning Chen, Meina Cui, Suping Ma, Xiaoyu Hao, Liwei Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent |
title | Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent |
title_full | Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent |
title_fullStr | Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent |
title_full_unstemmed | Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent |
title_short | Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent |
title_sort | desulfurization and denitrification performance of modified rice husk ash-carbide slag absorbent |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795989/ https://www.ncbi.nlm.nih.gov/pubmed/33375696 http://dx.doi.org/10.3390/ma14010068 |
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