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Selective Conversion of Scenedesmus into Lactic Acid over Amine-Modified Sn-β

[Image: see text] Amine-modified Sn-β was synthesized to improve the yield of lactic acid produced from Scenedesmus. After studying the growth of Scenedesmus, we selected Scenedesmus with the highest sugar content of 46.7% after 8 days of culture as the reaction substrate. The results showed that th...

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Detalles Bibliográficos
Autores principales: Shen, Zheng, Gao, Yishan, Kong, Ling, Gu, Minyan, Xia, Meng, Dong, Wenjie, Zhang, Wei, Zhou, Xuefei, Zhang, Yalei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7807806/
https://www.ncbi.nlm.nih.gov/pubmed/33458480
http://dx.doi.org/10.1021/acsomega.0c04561
Descripción
Sumario:[Image: see text] Amine-modified Sn-β was synthesized to improve the yield of lactic acid produced from Scenedesmus. After studying the growth of Scenedesmus, we selected Scenedesmus with the highest sugar content of 46.7% after 8 days of culture as the reaction substrate. The results showed that the yield of lactic acid from Scenedesmus was greatly increased after being catalyzed by 3-aminopropyltrimethoxysilane (APTMS)-modified Sn-β. After the pretreatment of Scenedesmus in an ice bath ultrasound, under the optimal reaction conditions (190 °C and 5 h), the yield of lactic acid reached the highest (37%). The acid–base characterization results of the catalyst confirmed that there are both Lewis acidic sites and medium-strength basic sites in the catalyst. Both of these sites can promote the hydrolysis of Scenedesmus, while the Lewis acidic sites can promote the production of lactic acid and the basic sites can effectively inhibit the production of the byproduct 5-hydroxymethylfurfural (HMF). This study proved that this amination catalyst is a useful strategy to increase the yield of lactic acid.