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Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity

[Image: see text] Zinc oxide is one of the novel metal oxides utilized for diverse applications. The sol–gel and unintended self-propagation procedures were applied to synthesize the porous and high surface area ZnO-based metal oxide nanocomposite. The p-type manganese(III) oxide was successfully co...

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Autores principales: Abebe, Buzuayehu, Zereffa, Enyew A., Murthy, H C Ananda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7808141/
https://www.ncbi.nlm.nih.gov/pubmed/33458547
http://dx.doi.org/10.1021/acsomega.0c05597
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author Abebe, Buzuayehu
Zereffa, Enyew A.
Murthy, H C Ananda
author_facet Abebe, Buzuayehu
Zereffa, Enyew A.
Murthy, H C Ananda
author_sort Abebe, Buzuayehu
collection PubMed
description [Image: see text] Zinc oxide is one of the novel metal oxides utilized for diverse applications. The sol–gel and unintended self-propagation procedures were applied to synthesize the porous and high surface area ZnO-based metal oxide nanocomposite. The p-type manganese(III) oxide was successfully coupled with n-type ZnO. The physical property characterization results revealed the surface area, porosity, and charge transfer capability improvement on the poly(vinyl alcohol) (PVA)-aided binary nanocomposite (PVA-ZnO/Mn(2)O(3)), compared to ZnO. The XRD patterns and TEM image analysis validated the nanometer size range for the materials (15–60 nm). The SEM micrographs and BET spectral details have confirmed the porous nature of the PVA-ZnO/Mn(2)O(3) nanocomposite. The supporting results were obtained from the HRTEM (IFFT) and SAED pattern analyses. The EDX and HRTEM analyses were used for the confirmation of elemental composition and reality of the PVA-ZnO/Mn(2)O(3) composite, respectively. The presence of the improved charge transfer property for PVA-ZnO/Mn(2)O(3), compared to ZnO, was evidenced from acid orange-8 dye degradation. The highest zone of inhibition (14 mm) was recorded on Escherichia coli bacteria for the uncalcined PVA-ZnO/Mn(2)O(3) nanocomposite compared to PVA, yet, less zone of inhibition compared to the calcined PVA-ZnO/Mn(2)O(3) nanocomposite. The authors recommend the formation of the couple between metal oxides by electrochemical technique analyses as a future work.
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spelling pubmed-78081412021-01-15 Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity Abebe, Buzuayehu Zereffa, Enyew A. Murthy, H C Ananda ACS Omega [Image: see text] Zinc oxide is one of the novel metal oxides utilized for diverse applications. The sol–gel and unintended self-propagation procedures were applied to synthesize the porous and high surface area ZnO-based metal oxide nanocomposite. The p-type manganese(III) oxide was successfully coupled with n-type ZnO. The physical property characterization results revealed the surface area, porosity, and charge transfer capability improvement on the poly(vinyl alcohol) (PVA)-aided binary nanocomposite (PVA-ZnO/Mn(2)O(3)), compared to ZnO. The XRD patterns and TEM image analysis validated the nanometer size range for the materials (15–60 nm). The SEM micrographs and BET spectral details have confirmed the porous nature of the PVA-ZnO/Mn(2)O(3) nanocomposite. The supporting results were obtained from the HRTEM (IFFT) and SAED pattern analyses. The EDX and HRTEM analyses were used for the confirmation of elemental composition and reality of the PVA-ZnO/Mn(2)O(3) composite, respectively. The presence of the improved charge transfer property for PVA-ZnO/Mn(2)O(3), compared to ZnO, was evidenced from acid orange-8 dye degradation. The highest zone of inhibition (14 mm) was recorded on Escherichia coli bacteria for the uncalcined PVA-ZnO/Mn(2)O(3) nanocomposite compared to PVA, yet, less zone of inhibition compared to the calcined PVA-ZnO/Mn(2)O(3) nanocomposite. The authors recommend the formation of the couple between metal oxides by electrochemical technique analyses as a future work. American Chemical Society 2020-12-24 /pmc/articles/PMC7808141/ /pubmed/33458547 http://dx.doi.org/10.1021/acsomega.0c05597 Text en © 2020 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Abebe, Buzuayehu
Zereffa, Enyew A.
Murthy, H C Ananda
Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity
title Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity
title_full Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity
title_fullStr Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity
title_full_unstemmed Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity
title_short Synthesis of Poly(vinyl alcohol)-Aided ZnO/Mn(2)O(3) Nanocomposites for Acid Orange-8 Dye Degradation: Mechanism and Antibacterial Activity
title_sort synthesis of poly(vinyl alcohol)-aided zno/mn(2)o(3) nanocomposites for acid orange-8 dye degradation: mechanism and antibacterial activity
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7808141/
https://www.ncbi.nlm.nih.gov/pubmed/33458547
http://dx.doi.org/10.1021/acsomega.0c05597
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