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Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals
Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant metal complexes generate stabilized and unstabilized carbon-centered radicals from alkenes of various substitution patterns with rob...
Autores principales: | Shevick, Sophia L., Wilson, Conner V., Kotesova, Simona, Kim, Dongyoung, Holland, Patrick L., Shenvi, Ryan A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7810138/ https://www.ncbi.nlm.nih.gov/pubmed/33520153 http://dx.doi.org/10.1039/d0sc04112b |
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