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Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers

Critical-like behaviors have been found in translational degrees of freedom near the glass transition of spherical particle systems mainly with local polycrystalline structures, but it is not clear if criticality exists in more general glassy systems composed of nonspherical particles without crysta...

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Autores principales: Zheng, Zhongyu, Ni, Ran, Wang, Yuren, Han, Yilong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7810379/
https://www.ncbi.nlm.nih.gov/pubmed/33523902
http://dx.doi.org/10.1126/sciadv.abd1958
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author Zheng, Zhongyu
Ni, Ran
Wang, Yuren
Han, Yilong
author_facet Zheng, Zhongyu
Ni, Ran
Wang, Yuren
Han, Yilong
author_sort Zheng, Zhongyu
collection PubMed
description Critical-like behaviors have been found in translational degrees of freedom near the glass transition of spherical particle systems mainly with local polycrystalline structures, but it is not clear if criticality exists in more general glassy systems composed of nonspherical particles without crystalline structures. Here, through experiments and simulations, we show critical-like behaviors in both translational and rotational degrees of freedom in monolayers of monodisperse colloidal ellipsoids in the absence of crystalline orders. We find rich features of the Ising-like criticality in structure and slow dynamics at the ideal glass transition point ϕ(0), showing the thermodynamic nature of glass transition at ϕ(0). A dynamic criticality is found at the mode-coupling critical point ϕ(c) for the fast-moving clusters whose critical exponents increase linearly with fragility, reflecting a dynamic glass transition. These results cast light on the glass transition and explain the mystery that the dynamic correlation lengths diverge at two different temperatures.
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spelling pubmed-78103792021-01-22 Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers Zheng, Zhongyu Ni, Ran Wang, Yuren Han, Yilong Sci Adv Research Articles Critical-like behaviors have been found in translational degrees of freedom near the glass transition of spherical particle systems mainly with local polycrystalline structures, but it is not clear if criticality exists in more general glassy systems composed of nonspherical particles without crystalline structures. Here, through experiments and simulations, we show critical-like behaviors in both translational and rotational degrees of freedom in monolayers of monodisperse colloidal ellipsoids in the absence of crystalline orders. We find rich features of the Ising-like criticality in structure and slow dynamics at the ideal glass transition point ϕ(0), showing the thermodynamic nature of glass transition at ϕ(0). A dynamic criticality is found at the mode-coupling critical point ϕ(c) for the fast-moving clusters whose critical exponents increase linearly with fragility, reflecting a dynamic glass transition. These results cast light on the glass transition and explain the mystery that the dynamic correlation lengths diverge at two different temperatures. American Association for the Advancement of Science 2021-01-15 /pmc/articles/PMC7810379/ /pubmed/33523902 http://dx.doi.org/10.1126/sciadv.abd1958 Text en Copyright © 2021 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). https://creativecommons.org/licenses/by-nc/4.0/ https://creativecommons.org/licenses/by-nc/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (https://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.
spellingShingle Research Articles
Zheng, Zhongyu
Ni, Ran
Wang, Yuren
Han, Yilong
Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
title Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
title_full Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
title_fullStr Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
title_full_unstemmed Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
title_short Translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
title_sort translational and rotational critical-like behaviors in the glass transition of colloidal ellipsoid monolayers
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7810379/
https://www.ncbi.nlm.nih.gov/pubmed/33523902
http://dx.doi.org/10.1126/sciadv.abd1958
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