Comparison of different models to calculate the viscosity of biogas and biomethane in order to accurately measure flow rates for conformity assessment

The study presents an optimised method to correct flow rates measured with a LFE flowmeter pre-set on methane while used for gas mixtures of unknown composition at the time of the measurement. The method requires the correction of the flow rate using a factor based on the viscosity of the gas mixtures once the composition is accurately known. The method has several different possible applications inclusive for the sampling of biogas and biomethane onto sorbent tubes for conformity assessment for the determination of siloxanes, terpenes and VOC in general. Five models for the calculation of the viscosity of the gas mixtures were compared and the models were used for ten binary mixtures and four multi-component mixtures. The results of the evaluation of the different models showed that the correction method using the viscosity of the mixtures calculated with the model of Reichenberg and Carr showed the smallest biases for binary mixtures. For multi-component mixtures, the best results were obtained when using the models of Lucas and Carr.