SC–SC Anion-Assisted Linker Exchange within a Three-Dimensional Cu(II)-Triazole Framework: A Luminescent Probe for S(2–)

[Image: see text] A three-dimensional (3D) binodal 3,5-connected net, {[Cu(MTP)(H(2)O)](NO(3))}(n) (1) with the Schläfli symbol of {3·7(2)}{3(2)·7(5)·8(3)} can be transformed into a two-dimensional (2D) kagóme network with the Schlafli symbol of {3(2)·6(2)·7(2)} in an irreversible single crystal–sin...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Gong, Shuang-Shuang, Liu, Yue, Cheng, Lin, Li, Shuang-Shuang, Zhang, Ying, Cui, Yukun, Liang, Chenlu, Tang, Li, Ren, Peng, Fang, Yu, Day, Gregory S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7818306/
https://www.ncbi.nlm.nih.gov/pubmed/33490785
http://dx.doi.org/10.1021/acsomega.0c04676
Descripción
Sumario:[Image: see text] A three-dimensional (3D) binodal 3,5-connected net, {[Cu(MTP)(H(2)O)](NO(3))}(n) (1) with the Schläfli symbol of {3·7(2)}{3(2)·7(5)·8(3)} can be transformed into a two-dimensional (2D) kagóme network with the Schlafli symbol of {3(2)·6(2)·7(2)} in an irreversible single crystal–single crystal (SC–SC) guest-assisted linker exchange process. The product of this SC–SC represents the first luminescent probe for S(2–) based on triazole ligand.

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