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Molecular Bismuth Cations: Assessment of Soft Lewis Acidity
Three‐coordinate cationic bismuth compounds [Bi(diaryl)(EPMe(3))][SbF(6)] have been isolated and fully characterized (diaryl=[(C(6)H(4))(2)C(2)H(2)](2−), E=S, Se). They represent rare examples of molecular complexes with Bi⋅⋅⋅EPR(3) interactions (R=monoanionic substituent). The (31)P NMR chemical sh...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7818483/ https://www.ncbi.nlm.nih.gov/pubmed/32428329 http://dx.doi.org/10.1002/chem.202001674 |