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Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil

[Image: see text] As an important component of crude oil, asphaltene precipitation and deposition are harmful to petroleum production and processing. In previous research, the impacts of asphaltene precipitation on crude oil characteristics were preliminarily explored. In this paper, by mixing diffe...

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Autores principales: Lei, Yun, Yu, Pengfei, Ni, Wenqiang, Peng, Haoping, Liu, Yang, Lv, Xiaofang, Zhao, Huijun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7818607/
https://www.ncbi.nlm.nih.gov/pubmed/33490809
http://dx.doi.org/10.1021/acsomega.0c05121
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author Lei, Yun
Yu, Pengfei
Ni, Wenqiang
Peng, Haoping
Liu, Yang
Lv, Xiaofang
Zhao, Huijun
author_facet Lei, Yun
Yu, Pengfei
Ni, Wenqiang
Peng, Haoping
Liu, Yang
Lv, Xiaofang
Zhao, Huijun
author_sort Lei, Yun
collection PubMed
description [Image: see text] As an important component of crude oil, asphaltene precipitation and deposition are harmful to petroleum production and processing. In previous research, the impacts of asphaltene precipitation on crude oil characteristics were preliminarily explored. In this paper, by mixing different types of crude oil, the dynamic process of asphaltene precipitation and its effect on the crystallization and gelation behaviors of mixed crude oil were in-depth analyzed and discussed using the high-speed centrifugation technique, microscopic observation, differential scanning calorimetry (DSC) thermal analysis, and rheological test. The results showed that the asphaltene precipitation mainly occurred in the early stage of crude oil mixing and was influenced by crude oil composition. As the precipitation time increased, the driving force for asphaltene precipitation was gradually weakened until a dynamic equilibrium between asphaltene precipitation and dissolution was reached. Meanwhile, once the asphaltene precipitation occurred, the crystallization and gelation processes of crude oil were significantly affected. It was discovered that the change in the existing state of asphaltenes due to their precipitation is an important factor affecting the interaction of asphaltenes and waxes, which is critical for the technological development of oil and gas flow assurance.
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spelling pubmed-78186072021-01-22 Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil Lei, Yun Yu, Pengfei Ni, Wenqiang Peng, Haoping Liu, Yang Lv, Xiaofang Zhao, Huijun ACS Omega [Image: see text] As an important component of crude oil, asphaltene precipitation and deposition are harmful to petroleum production and processing. In previous research, the impacts of asphaltene precipitation on crude oil characteristics were preliminarily explored. In this paper, by mixing different types of crude oil, the dynamic process of asphaltene precipitation and its effect on the crystallization and gelation behaviors of mixed crude oil were in-depth analyzed and discussed using the high-speed centrifugation technique, microscopic observation, differential scanning calorimetry (DSC) thermal analysis, and rheological test. The results showed that the asphaltene precipitation mainly occurred in the early stage of crude oil mixing and was influenced by crude oil composition. As the precipitation time increased, the driving force for asphaltene precipitation was gradually weakened until a dynamic equilibrium between asphaltene precipitation and dissolution was reached. Meanwhile, once the asphaltene precipitation occurred, the crystallization and gelation processes of crude oil were significantly affected. It was discovered that the change in the existing state of asphaltenes due to their precipitation is an important factor affecting the interaction of asphaltenes and waxes, which is critical for the technological development of oil and gas flow assurance. American Chemical Society 2021-01-07 /pmc/articles/PMC7818607/ /pubmed/33490809 http://dx.doi.org/10.1021/acsomega.0c05121 Text en © 2021 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Lei, Yun
Yu, Pengfei
Ni, Wenqiang
Peng, Haoping
Liu, Yang
Lv, Xiaofang
Zhao, Huijun
Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil
title Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil
title_full Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil
title_fullStr Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil
title_full_unstemmed Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil
title_short Study on the Kinetic Process of Asphaltene Precipitation during Crude Oil Mixing and Its Effect on the Wax Behavior of Crude Oil
title_sort study on the kinetic process of asphaltene precipitation during crude oil mixing and its effect on the wax behavior of crude oil
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7818607/
https://www.ncbi.nlm.nih.gov/pubmed/33490809
http://dx.doi.org/10.1021/acsomega.0c05121
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