A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?

The earth‐metal olefin complex [Ga(I)(COD)(2)](+)[Al(OR(F))(4)](−) (COD=1,5‐cyclooctadiene; R(F)=C(CF(3))(3)) constitutes the first homoleptic olefin complex of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and constitutes an olefin complex of a...

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Detalles Bibliográficos
Autores principales: Glootz, Kim, Barthélemy, Antoine, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7820946/
https://www.ncbi.nlm.nih.gov/pubmed/32959513
http://dx.doi.org/10.1002/anie.202011466
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author Glootz, Kim
Barthélemy, Antoine
Krossing, Ingo
author_facet Glootz, Kim
Barthélemy, Antoine
Krossing, Ingo
author_sort Glootz, Kim
collection PubMed
description The earth‐metal olefin complex [Ga(I)(COD)(2)](+)[Al(OR(F))(4)](−) (COD=1,5‐cyclooctadiene; R(F)=C(CF(3))(3)) constitutes the first homoleptic olefin complex of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and constitutes an olefin complex of a main‐group metal that—similar to many transition‐metals—may adopt the +1 and +3 oxidation states opening potential applications. Crystallographic‐, vibrational‐ and computational investigations give an insight to the atypical bonding between an olefin and a main‐group metal. They are compared to classical transition‐metal relatives.
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spelling pubmed-78209462021-01-26 A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal? Glootz, Kim Barthélemy, Antoine Krossing, Ingo Angew Chem Int Ed Engl Communications The earth‐metal olefin complex [Ga(I)(COD)(2)](+)[Al(OR(F))(4)](−) (COD=1,5‐cyclooctadiene; R(F)=C(CF(3))(3)) constitutes the first homoleptic olefin complex of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and constitutes an olefin complex of a main‐group metal that—similar to many transition‐metals—may adopt the +1 and +3 oxidation states opening potential applications. Crystallographic‐, vibrational‐ and computational investigations give an insight to the atypical bonding between an olefin and a main‐group metal. They are compared to classical transition‐metal relatives. John Wiley and Sons Inc. 2020-10-27 2021-01-04 /pmc/articles/PMC7820946/ /pubmed/32959513 http://dx.doi.org/10.1002/anie.202011466 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Glootz, Kim
Barthélemy, Antoine
Krossing, Ingo
A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
title A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
title_full A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
title_fullStr A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
title_full_unstemmed A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
title_short A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
title_sort simple homoleptic gallium(i) olefin complex: mimicking transition‐metal chemistry at a main‐group metal?
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7820946/
https://www.ncbi.nlm.nih.gov/pubmed/32959513
http://dx.doi.org/10.1002/anie.202011466
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