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Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols

The direct, catalytic dehydrative substitution of alcohols is a challenging, yet highly desirable process in the development of more sustainable approaches to organic chemistry. This review outlines recent advances in Brønsted acid‐catalysed dehydrative substitution reactions for C−C, C−O, C−N and C...

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Detalles Bibliográficos
Autores principales: Estopiñá‐Durán, Susana, Taylor, James E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7820959/
https://www.ncbi.nlm.nih.gov/pubmed/32491202
http://dx.doi.org/10.1002/chem.202002106
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author Estopiñá‐Durán, Susana
Taylor, James E.
author_facet Estopiñá‐Durán, Susana
Taylor, James E.
author_sort Estopiñá‐Durán, Susana
collection PubMed
description The direct, catalytic dehydrative substitution of alcohols is a challenging, yet highly desirable process in the development of more sustainable approaches to organic chemistry. This review outlines recent advances in Brønsted acid‐catalysed dehydrative substitution reactions for C−C, C−O, C−N and C−S bond formation. The wide range of processes that are now accessible using simple alcohols as the formal electrophile are highlighted, while current limitations and therefore possible future directions for research are also discussed.
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spelling pubmed-78209592021-01-26 Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols Estopiñá‐Durán, Susana Taylor, James E. Chemistry Minireviews The direct, catalytic dehydrative substitution of alcohols is a challenging, yet highly desirable process in the development of more sustainable approaches to organic chemistry. This review outlines recent advances in Brønsted acid‐catalysed dehydrative substitution reactions for C−C, C−O, C−N and C−S bond formation. The wide range of processes that are now accessible using simple alcohols as the formal electrophile are highlighted, while current limitations and therefore possible future directions for research are also discussed. John Wiley and Sons Inc. 2020-10-15 2021-01-04 /pmc/articles/PMC7820959/ /pubmed/32491202 http://dx.doi.org/10.1002/chem.202002106 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Minireviews
Estopiñá‐Durán, Susana
Taylor, James E.
Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols
title Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols
title_full Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols
title_fullStr Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols
title_full_unstemmed Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols
title_short Brønsted Acid‐Catalysed Dehydrative Substitution Reactions of Alcohols
title_sort brønsted acid‐catalysed dehydrative substitution reactions of alcohols
topic Minireviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7820959/
https://www.ncbi.nlm.nih.gov/pubmed/32491202
http://dx.doi.org/10.1002/chem.202002106
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