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Hydrogen Bonding Enhances the Electrochemical Hydrogenation of Benzaldehyde in the Aqueous Phase

The hydrogenation of benzaldehyde to benzyl alcohol on carbon‐supported metals in water, enabled by an external potential, is markedly promoted by polarization of the functional groups. The presence of polar co‐adsorbates, such as substituted phenols, enhances the hydrogenation rate of the aldehyde...

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Detalles Bibliográficos
Autores principales: Sanyal, Udishnu, Yuk, Simuck F., Koh, Katherine, Lee, Mal‐Soon, Stoerzinger, Kelsey, Zhang, Difan, Meyer, Laura C., Lopez‐Ruiz, Juan A., Karkamkar, Abhi, Holladay, Jamie D., Camaioni, Donald M., Nguyen, Manh‐Thuong, Glezakou, Vassiliki‐Alexandra, Rousseau, Roger, Gutiérrez, Oliver Y., Lercher, Johannes A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7821193/
https://www.ncbi.nlm.nih.gov/pubmed/32770641
http://dx.doi.org/10.1002/anie.202008178