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Hydrogen Bonding Enhances the Electrochemical Hydrogenation of Benzaldehyde in the Aqueous Phase
The hydrogenation of benzaldehyde to benzyl alcohol on carbon‐supported metals in water, enabled by an external potential, is markedly promoted by polarization of the functional groups. The presence of polar co‐adsorbates, such as substituted phenols, enhances the hydrogenation rate of the aldehyde...
Autores principales: | Sanyal, Udishnu, Yuk, Simuck F., Koh, Katherine, Lee, Mal‐Soon, Stoerzinger, Kelsey, Zhang, Difan, Meyer, Laura C., Lopez‐Ruiz, Juan A., Karkamkar, Abhi, Holladay, Jamie D., Camaioni, Donald M., Nguyen, Manh‐Thuong, Glezakou, Vassiliki‐Alexandra, Rousseau, Roger, Gutiérrez, Oliver Y., Lercher, Johannes A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7821193/ https://www.ncbi.nlm.nih.gov/pubmed/32770641 http://dx.doi.org/10.1002/anie.202008178 |
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