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Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating

Due to its special two-dimensional lamellar structure, graphene possesses an excellent shielding effect, hydrophobic characteristics and large specific surface area, which can effectively isolate the internal structure from the external corrosive media. However, lamellar graphene is easy to stack an...

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Autores principales: Liu, Xiaoyan, Jie, Handuo, Liu, Ruidan, Liu, Yanqi, Li, Tianyu, Lyu, Kai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7825610/
https://www.ncbi.nlm.nih.gov/pubmed/33419213
http://dx.doi.org/10.3390/polym13020183
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author Liu, Xiaoyan
Jie, Handuo
Liu, Ruidan
Liu, Yanqi
Li, Tianyu
Lyu, Kai
author_facet Liu, Xiaoyan
Jie, Handuo
Liu, Ruidan
Liu, Yanqi
Li, Tianyu
Lyu, Kai
author_sort Liu, Xiaoyan
collection PubMed
description Due to its special two-dimensional lamellar structure, graphene possesses an excellent shielding effect, hydrophobic characteristics and large specific surface area, which can effectively isolate the internal structure from the external corrosive media. However, lamellar graphene is easy to stack and agglomerate, which limits its anti-corrosion performance. In this paper, cerium oxide-graphene oxide (CeO(2)-GO) nanocomposites were prepared by a hydrothermal synthesis method. Field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM) were applied for microstructure examination, showing that a large number of nanoscale granular cerium oxide grew on the lamellar graphene oxide surface, which improved the dispersion performance of graphene inside the matrix. The anti-corrosion properties of the coating were analyzed and illustrated by open circuit potential (OCP), frequency response analysis, Tafel curve and Mott–Schottky curve. The results indicated that the CeO(2)-GO (4:1) nanocomposite not only eliminated the agglomeration of graphene to some extent, but also prepared the graphene epoxy coating with good dispersion, which further promoted its anti-corrosion performance. The paper proposed a feasible solution for GO dispersion in cement-based materials and lays a solid theoretical foundation for the engineering application of cerium oxide-graphene oxide modified anticorrosive coating.
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spelling pubmed-78256102021-01-24 Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating Liu, Xiaoyan Jie, Handuo Liu, Ruidan Liu, Yanqi Li, Tianyu Lyu, Kai Polymers (Basel) Article Due to its special two-dimensional lamellar structure, graphene possesses an excellent shielding effect, hydrophobic characteristics and large specific surface area, which can effectively isolate the internal structure from the external corrosive media. However, lamellar graphene is easy to stack and agglomerate, which limits its anti-corrosion performance. In this paper, cerium oxide-graphene oxide (CeO(2)-GO) nanocomposites were prepared by a hydrothermal synthesis method. Field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM) were applied for microstructure examination, showing that a large number of nanoscale granular cerium oxide grew on the lamellar graphene oxide surface, which improved the dispersion performance of graphene inside the matrix. The anti-corrosion properties of the coating were analyzed and illustrated by open circuit potential (OCP), frequency response analysis, Tafel curve and Mott–Schottky curve. The results indicated that the CeO(2)-GO (4:1) nanocomposite not only eliminated the agglomeration of graphene to some extent, but also prepared the graphene epoxy coating with good dispersion, which further promoted its anti-corrosion performance. The paper proposed a feasible solution for GO dispersion in cement-based materials and lays a solid theoretical foundation for the engineering application of cerium oxide-graphene oxide modified anticorrosive coating. MDPI 2021-01-06 /pmc/articles/PMC7825610/ /pubmed/33419213 http://dx.doi.org/10.3390/polym13020183 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liu, Xiaoyan
Jie, Handuo
Liu, Ruidan
Liu, Yanqi
Li, Tianyu
Lyu, Kai
Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating
title Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating
title_full Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating
title_fullStr Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating
title_full_unstemmed Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating
title_short Research on the Preparation and Anticorrosion Properties of EP/CeO(2)-GO Nanocomposite Coating
title_sort research on the preparation and anticorrosion properties of ep/ceo(2)-go nanocomposite coating
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7825610/
https://www.ncbi.nlm.nih.gov/pubmed/33419213
http://dx.doi.org/10.3390/polym13020183
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