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Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors

The in situ spectroelectrochemical cyclic voltammetric studies of the antimony-monocapped nickel(II) and iron(II) tris-pyridineoximates with a labile triethylantimony cross-linking group and Zr(IV)/Hf(IV) phthalocyaninate complexes were performed in order to understand the nature of the redox events...

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Autores principales: Voloshin, Yan Z., Dudkin, Semyon V., Belova, Svetlana A., Gherca, Daniel, Samohvalov, Dumitru, Manta, Corina-Mihaela, Lungan, Maria-Andreea, Meier-Menches, Samuel M., Rapta, Peter, Darvasiová, Denisa, Malček, Michal, Pombeiro, Armando J. L., Martins, Luísa M. D. R. S., Arion, Vladimir B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7827310/
https://www.ncbi.nlm.nih.gov/pubmed/33440755
http://dx.doi.org/10.3390/molecules26020336
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author Voloshin, Yan Z.
Dudkin, Semyon V.
Belova, Svetlana A.
Gherca, Daniel
Samohvalov, Dumitru
Manta, Corina-Mihaela
Lungan, Maria-Andreea
Meier-Menches, Samuel M.
Rapta, Peter
Darvasiová, Denisa
Malček, Michal
Pombeiro, Armando J. L.
Martins, Luísa M. D. R. S.
Arion, Vladimir B.
author_facet Voloshin, Yan Z.
Dudkin, Semyon V.
Belova, Svetlana A.
Gherca, Daniel
Samohvalov, Dumitru
Manta, Corina-Mihaela
Lungan, Maria-Andreea
Meier-Menches, Samuel M.
Rapta, Peter
Darvasiová, Denisa
Malček, Michal
Pombeiro, Armando J. L.
Martins, Luísa M. D. R. S.
Arion, Vladimir B.
author_sort Voloshin, Yan Z.
collection PubMed
description The in situ spectroelectrochemical cyclic voltammetric studies of the antimony-monocapped nickel(II) and iron(II) tris-pyridineoximates with a labile triethylantimony cross-linking group and Zr(IV)/Hf(IV) phthalocyaninate complexes were performed in order to understand the nature of the redox events in the molecules of heterodinuclear zirconium(IV) and hafnium(IV) phthalocyaninate-capped derivatives. Electronic structures of their 1e-oxidized and 1e-electron-reduced forms were experimentally studied by electron paramagnetic resonance (EPR) spectroscopy and UV−vis−near-IR spectroelectrochemical experiments and supported by density functional theory (DFT) calculations. The investigated hybrid molecular systems that combine a transition metal (pseudo)clathrochelate and a Zr/Hf-phthalocyaninate moiety exhibit quite rich redox activity both in the cathodic and in the anodic region. These binuclear compounds and their precursors were tested as potential catalysts in oxidation reactions of cyclohexane and the results are discussed.
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spelling pubmed-78273102021-01-25 Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors Voloshin, Yan Z. Dudkin, Semyon V. Belova, Svetlana A. Gherca, Daniel Samohvalov, Dumitru Manta, Corina-Mihaela Lungan, Maria-Andreea Meier-Menches, Samuel M. Rapta, Peter Darvasiová, Denisa Malček, Michal Pombeiro, Armando J. L. Martins, Luísa M. D. R. S. Arion, Vladimir B. Molecules Article The in situ spectroelectrochemical cyclic voltammetric studies of the antimony-monocapped nickel(II) and iron(II) tris-pyridineoximates with a labile triethylantimony cross-linking group and Zr(IV)/Hf(IV) phthalocyaninate complexes were performed in order to understand the nature of the redox events in the molecules of heterodinuclear zirconium(IV) and hafnium(IV) phthalocyaninate-capped derivatives. Electronic structures of their 1e-oxidized and 1e-electron-reduced forms were experimentally studied by electron paramagnetic resonance (EPR) spectroscopy and UV−vis−near-IR spectroelectrochemical experiments and supported by density functional theory (DFT) calculations. The investigated hybrid molecular systems that combine a transition metal (pseudo)clathrochelate and a Zr/Hf-phthalocyaninate moiety exhibit quite rich redox activity both in the cathodic and in the anodic region. These binuclear compounds and their precursors were tested as potential catalysts in oxidation reactions of cyclohexane and the results are discussed. MDPI 2021-01-11 /pmc/articles/PMC7827310/ /pubmed/33440755 http://dx.doi.org/10.3390/molecules26020336 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Voloshin, Yan Z.
Dudkin, Semyon V.
Belova, Svetlana A.
Gherca, Daniel
Samohvalov, Dumitru
Manta, Corina-Mihaela
Lungan, Maria-Andreea
Meier-Menches, Samuel M.
Rapta, Peter
Darvasiová, Denisa
Malček, Michal
Pombeiro, Armando J. L.
Martins, Luísa M. D. R. S.
Arion, Vladimir B.
Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
title Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
title_full Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
title_fullStr Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
title_full_unstemmed Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
title_short Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
title_sort spectroelectrochemical properties and catalytic activity in cyclohexane oxidation of the hybrid zr/hf-phthalocyaninate-capped nickel(ii) and iron(ii) tris-pyridineoximates and their precursors
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7827310/
https://www.ncbi.nlm.nih.gov/pubmed/33440755
http://dx.doi.org/10.3390/molecules26020336
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