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Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature

Gas sensors are fundamental for continuous online monitoring of volatile organic compounds. Gas sensors based on semiconductor materials have demonstrated to be highly competitive, but are generally made of expensive materials and operate at high temperatures, which are drawbacks of these technologi...

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Autores principales: Garcia-Osorio, Daniel, Hidalgo-Falla, Pilar, Peres, Henrique E. M., Gonçalves, Josue M., Araki, Koiti, Garcia-Segura, Sergi, Picasso, Gino
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7827617/
https://www.ncbi.nlm.nih.gov/pubmed/33435484
http://dx.doi.org/10.3390/s21020440
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author Garcia-Osorio, Daniel
Hidalgo-Falla, Pilar
Peres, Henrique E. M.
Gonçalves, Josue M.
Araki, Koiti
Garcia-Segura, Sergi
Picasso, Gino
author_facet Garcia-Osorio, Daniel
Hidalgo-Falla, Pilar
Peres, Henrique E. M.
Gonçalves, Josue M.
Araki, Koiti
Garcia-Segura, Sergi
Picasso, Gino
author_sort Garcia-Osorio, Daniel
collection PubMed
description Gas sensors are fundamental for continuous online monitoring of volatile organic compounds. Gas sensors based on semiconductor materials have demonstrated to be highly competitive, but are generally made of expensive materials and operate at high temperatures, which are drawbacks of these technologies. Herein is described a novel ethanol sensor for room temperature (25 °C) measurements based on hematite (α‑Fe(2)O(3))/silver nanoparticles. The AgNPs were shown to increase the oxide semiconductor charge carrier density, but especially to enhance the ethanol adsorption rate boosting the selectivity and sensitivity, thus allowing quantification of ethanol vapor in 2–35 mg L(−1) range with an excellent linear relationship. In addition, the α-Fe(2)O(3)/Ag 3.0 wt% nanocomposite is cheap, and easy to make and process, imparting high perspectives for real applications in breath analyzers and/or sensors in food and beverage industries. This work contributes to the advance of gas sensing at ambient temperature as a competitive alternative for quantification of conventional volatile organic compounds.
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spelling pubmed-78276172021-01-25 Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature Garcia-Osorio, Daniel Hidalgo-Falla, Pilar Peres, Henrique E. M. Gonçalves, Josue M. Araki, Koiti Garcia-Segura, Sergi Picasso, Gino Sensors (Basel) Article Gas sensors are fundamental for continuous online monitoring of volatile organic compounds. Gas sensors based on semiconductor materials have demonstrated to be highly competitive, but are generally made of expensive materials and operate at high temperatures, which are drawbacks of these technologies. Herein is described a novel ethanol sensor for room temperature (25 °C) measurements based on hematite (α‑Fe(2)O(3))/silver nanoparticles. The AgNPs were shown to increase the oxide semiconductor charge carrier density, but especially to enhance the ethanol adsorption rate boosting the selectivity and sensitivity, thus allowing quantification of ethanol vapor in 2–35 mg L(−1) range with an excellent linear relationship. In addition, the α-Fe(2)O(3)/Ag 3.0 wt% nanocomposite is cheap, and easy to make and process, imparting high perspectives for real applications in breath analyzers and/or sensors in food and beverage industries. This work contributes to the advance of gas sensing at ambient temperature as a competitive alternative for quantification of conventional volatile organic compounds. MDPI 2021-01-09 /pmc/articles/PMC7827617/ /pubmed/33435484 http://dx.doi.org/10.3390/s21020440 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Garcia-Osorio, Daniel
Hidalgo-Falla, Pilar
Peres, Henrique E. M.
Gonçalves, Josue M.
Araki, Koiti
Garcia-Segura, Sergi
Picasso, Gino
Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature
title Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature
title_full Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature
title_fullStr Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature
title_full_unstemmed Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature
title_short Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature
title_sort silver enhances hematite nanoparticles based ethanol sensor response and selectivity at room temperature
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7827617/
https://www.ncbi.nlm.nih.gov/pubmed/33435484
http://dx.doi.org/10.3390/s21020440
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