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Short-Chained Platinum Complex Catalyzed Hydrosilylation under Thermomorphic Conditions: Heterogeneous Phase Separation at Ice Temperature

Homogeneous catalysts PtCl(2)[5,5′-bis-(n-ClCF(2)(CF(2))(3)CH(2)OCH(2))-2,2′-bpy] (2A) and PtCl(2)[5,5′-bis-(n-HCF(2)(CF(2))(3)CH(2)OCH(2))-2,2′-bpy] (2B), which contained short fluorous chains, were synthesized and used in catalysis of hydrosilylation of alkynes. In these reactions the thermomorphi...

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Detalles Bibliográficos
Autores principales: Chiu, Chiao-Fan, Ho, Jinn-Hsuan, Tessema, Eskedar, Lu, Yijing, Shen, Chia-Rui, Lin, Chang-Wei, Lu, Norman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7828357/
https://www.ncbi.nlm.nih.gov/pubmed/33450888
http://dx.doi.org/10.3390/molecules26020378