Cargando…

Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine

This work details the scalable and solventless synthesis of a potential fully biobased monobenzoxazine resin derived from tyrosol and furfurylamine. The structure of the monomer was studied by nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR). The curing of the prec...

Descripción completa

Detalles Bibliográficos
Autores principales: Wen, Zhibin, Bonnaud, Leïla, Mincheva, Rosica, Dubois, Philippe, Raquez, Jean-Marie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7829698/
https://www.ncbi.nlm.nih.gov/pubmed/33477447
http://dx.doi.org/10.3390/ma14020440
_version_ 1783641228365004800
author Wen, Zhibin
Bonnaud, Leïla
Mincheva, Rosica
Dubois, Philippe
Raquez, Jean-Marie
author_facet Wen, Zhibin
Bonnaud, Leïla
Mincheva, Rosica
Dubois, Philippe
Raquez, Jean-Marie
author_sort Wen, Zhibin
collection PubMed
description This work details the scalable and solventless synthesis of a potential fully biobased monobenzoxazine resin derived from tyrosol and furfurylamine. The structure of the monomer was studied by nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR). The curing of the precursors was characterized by differential scanning calorimetry (DSC), rheological measurements, and thermogravimetric analysis (TGA). The properties of the resulting biobased polybenzoxazine were then determined by thermogravimetric analysis (TGA) and dynamic mechanical thermal analysis (DMA). A thermally stable resin was obtained with 5% and 10% weight-reduction-temperature (T(d5) and T(d10)) values of 349 and 395 °C, respectively, and a char yield of 53%. Moreover, the low melting temperature, low viscosity, and excellent thermomechanical behavior make this fully biobased resin a promising candidate for coating applications.
format Online
Article
Text
id pubmed-7829698
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-78296982021-01-26 Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine Wen, Zhibin Bonnaud, Leïla Mincheva, Rosica Dubois, Philippe Raquez, Jean-Marie Materials (Basel) Article This work details the scalable and solventless synthesis of a potential fully biobased monobenzoxazine resin derived from tyrosol and furfurylamine. The structure of the monomer was studied by nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR). The curing of the precursors was characterized by differential scanning calorimetry (DSC), rheological measurements, and thermogravimetric analysis (TGA). The properties of the resulting biobased polybenzoxazine were then determined by thermogravimetric analysis (TGA) and dynamic mechanical thermal analysis (DMA). A thermally stable resin was obtained with 5% and 10% weight-reduction-temperature (T(d5) and T(d10)) values of 349 and 395 °C, respectively, and a char yield of 53%. Moreover, the low melting temperature, low viscosity, and excellent thermomechanical behavior make this fully biobased resin a promising candidate for coating applications. MDPI 2021-01-18 /pmc/articles/PMC7829698/ /pubmed/33477447 http://dx.doi.org/10.3390/ma14020440 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wen, Zhibin
Bonnaud, Leïla
Mincheva, Rosica
Dubois, Philippe
Raquez, Jean-Marie
Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine
title Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine
title_full Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine
title_fullStr Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine
title_full_unstemmed Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine
title_short Development of Low-Viscosity and High-Performance Biobased Monobenzoxazine from Tyrosol and Furfurylamine
title_sort development of low-viscosity and high-performance biobased monobenzoxazine from tyrosol and furfurylamine
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7829698/
https://www.ncbi.nlm.nih.gov/pubmed/33477447
http://dx.doi.org/10.3390/ma14020440
work_keys_str_mv AT wenzhibin developmentoflowviscosityandhighperformancebiobasedmonobenzoxazinefromtyrosolandfurfurylamine
AT bonnaudleila developmentoflowviscosityandhighperformancebiobasedmonobenzoxazinefromtyrosolandfurfurylamine
AT minchevarosica developmentoflowviscosityandhighperformancebiobasedmonobenzoxazinefromtyrosolandfurfurylamine
AT duboisphilippe developmentoflowviscosityandhighperformancebiobasedmonobenzoxazinefromtyrosolandfurfurylamine
AT raquezjeanmarie developmentoflowviscosityandhighperformancebiobasedmonobenzoxazinefromtyrosolandfurfurylamine