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Synthesis of Poly(Trimethylene Carbonate) from Amine Group Initiation: Role of Urethane Bonds in the Crystallinity

Semi-crystalline poly(trimethylene carbonate) (PTMC) can be efficiently prepared by ring-opening polymerization (ROP) initiated by amine using various catalysts. More promising results were reached with the one-step process of stannous octanoate unlike the two-step one-pot reaction using TBD and MSA...

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Detalles Bibliográficos
Autores principales:	Brossier, Thomas, Volpi, Gael, Lapinte, Vincent, Blanquer, Sebastien
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7829917/ https://www.ncbi.nlm.nih.gov/pubmed/33467051 http://dx.doi.org/10.3390/polym13020280

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