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Hydroxylamine‐Derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron‐Catalyzed Preparation of Unprotected Sulfinamides from Thiols
An iron catalyzed reaction for the selective transformation of thiols (‐SH) to sulfinamides (‐SONH(2)) by a direct transfer of ‐O and free ‐NH(2) groups has been developed. The reaction operates under mild conditions using a bench stable hydroxylamine derived reagent, exhibits broad functional group...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839456/ https://www.ncbi.nlm.nih.gov/pubmed/32955152 http://dx.doi.org/10.1002/anie.202011138 |