Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond

An N‐heterocyclic‐carbene‐stabilized diboryne undergoes rapid, high‐yielding and catalyst‐free hydroamination reactions with primary amines, yielding 1‐amino‐2‐hydrodiborenes, which can be considered boron analogues of enamines. The electronics of the organic substituent at nitrogen influence the st...

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Detalles Bibliográficos
Autores principales: Brückner, Tobias, Heß, Merlin, Stennett, Tom E., Rempel, Anna, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839459/
https://www.ncbi.nlm.nih.gov/pubmed/33058434
http://dx.doi.org/10.1002/anie.202012101

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839459/
https://www.ncbi.nlm.nih.gov/pubmed/33058434
http://dx.doi.org/10.1002/anie.202012101

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