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Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond
An N‐heterocyclic‐carbene‐stabilized diboryne undergoes rapid, high‐yielding and catalyst‐free hydroamination reactions with primary amines, yielding 1‐amino‐2‐hydrodiborenes, which can be considered boron analogues of enamines. The electronics of the organic substituent at nitrogen influence the st...
Autores principales: | Brückner, Tobias, Heß, Merlin, Stennett, Tom E., Rempel, Anna, Braunschweig, Holger |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839459/ https://www.ncbi.nlm.nih.gov/pubmed/33058434 http://dx.doi.org/10.1002/anie.202012101 |
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