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A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis‐Pair and Reductive Elimination
The reactivity of the frustrated Lewis pair (FLP) (F(5)C(2))(3)SnCH(2)P(tBu)(2) (1) was investigated with respect to the activation of elemental hydrogen. The reaction of 1 at elevated hydrogen pressure afforded the intramolecular phosphonium stannate(II) (F(5)C(2))(2)SnCH(2)PH(tBu)(2) (3). It was c...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839681/ https://www.ncbi.nlm.nih.gov/pubmed/33016507 http://dx.doi.org/10.1002/chem.202004425 |