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Catalytic Chemoselective Sulfimidation with an Electrophilic [Co(III)(TAML)](−)‐Nitrene Radical Complex
The cobalt species PPh(4)[Co(III)(TAML(red))] is a competent and stable catalyst for the sulfimidation of (aryl)(alkyl)‐substituted sulfides with iminoiodinanes, reaching turnover numbers up to 900 and turnover frequencies of 640 min(−1) under mild and aerobic conditions. The sulfimidation proceeds...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839782/ https://www.ncbi.nlm.nih.gov/pubmed/32810326 http://dx.doi.org/10.1002/chem.202003566 |