The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O(−) Hydrogen Bond of Silanol‐Silanolate Anions

The reaction of a saline phosphazenium hydroxide hydrate with siloxanes led to a novel kind of silanol‐silanolate anions. The weakly coordinating behavior of the cation renders the formation of silanol‐silanolate hydrogen bonds possible, which otherwise suffer from detrimental silanolate–oxygen cati...

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Detalles Bibliográficos
Autores principales: Weitkamp, Robin F., Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839788/
https://www.ncbi.nlm.nih.gov/pubmed/33180359
http://dx.doi.org/10.1002/chem.202004236

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839788/
https://www.ncbi.nlm.nih.gov/pubmed/33180359
http://dx.doi.org/10.1002/chem.202004236

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