Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films

[Image: see text] Stacking layered metal hydroxide films parallel to a substrate is challenging. Here, we demonstrate a simple and rapid electrodeposition method for stacking magnesium hydroxide layered films. Room-temperature cathodic electrolysis (40 mA cm(–2)) in a Mg(NO(3))(2) aqueous solution i...

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Autores principales: Shinagawa, Tsutomu, Chigane, Masaya, Izaki, Masanobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7841930/
https://www.ncbi.nlm.nih.gov/pubmed/33521469
http://dx.doi.org/10.1021/acsomega.0c05619
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author Shinagawa, Tsutomu
Chigane, Masaya
Izaki, Masanobu
author_facet Shinagawa, Tsutomu
Chigane, Masaya
Izaki, Masanobu
author_sort Shinagawa, Tsutomu
collection PubMed
description [Image: see text] Stacking layered metal hydroxide films parallel to a substrate is challenging. Here, we demonstrate a simple and rapid electrodeposition method for stacking magnesium hydroxide layered films. Room-temperature cathodic electrolysis (40 mA cm(–2)) in a Mg(NO(3))(2) aqueous solution induces the deposition of ⟨001⟩-oriented Mg(OH)(x) layered films stacked parallel to the substrate at the deposition rate of ∼2 μm min(–1). The obtained Mg(OH)(x) layered films undergo an overall oriented transformation by heat treatment to form ⟨111⟩-oriented nanoporous MgO films.
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spelling pubmed-78419302021-01-29 Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films Shinagawa, Tsutomu Chigane, Masaya Izaki, Masanobu ACS Omega [Image: see text] Stacking layered metal hydroxide films parallel to a substrate is challenging. Here, we demonstrate a simple and rapid electrodeposition method for stacking magnesium hydroxide layered films. Room-temperature cathodic electrolysis (40 mA cm(–2)) in a Mg(NO(3))(2) aqueous solution induces the deposition of ⟨001⟩-oriented Mg(OH)(x) layered films stacked parallel to the substrate at the deposition rate of ∼2 μm min(–1). The obtained Mg(OH)(x) layered films undergo an overall oriented transformation by heat treatment to form ⟨111⟩-oriented nanoporous MgO films. American Chemical Society 2021-01-11 /pmc/articles/PMC7841930/ /pubmed/33521469 http://dx.doi.org/10.1021/acsomega.0c05619 Text en © 2021 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Shinagawa, Tsutomu
Chigane, Masaya
Izaki, Masanobu
Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films
title Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films
title_full Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films
title_fullStr Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films
title_full_unstemmed Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films
title_short Electrochemical Growth of Mg(OH)(x) Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films
title_sort electrochemical growth of mg(oh)(x) layered films stacked parallel to the substrates and their thermal conversion to (111)-oriented nanoporous mgo films
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7841930/
https://www.ncbi.nlm.nih.gov/pubmed/33521469
http://dx.doi.org/10.1021/acsomega.0c05619
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AT chiganemasaya electrochemicalgrowthofmgohxlayeredfilmsstackedparalleltothesubstratesandtheirthermalconversionto111orientednanoporousmgofilms
AT izakimasanobu electrochemicalgrowthofmgohxlayeredfilmsstackedparalleltothesubstratesandtheirthermalconversionto111orientednanoporousmgofilms

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