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Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes
[Image: see text] The synthesis, characterization, and catalytic activity of low-spin {CoNO}(8) pincer complexes of the type [Co(PCP)(NO)(H)] are described. These compounds are obtained either by reacting [Co(PCP)(κ(2)-BH(4))] with NO and Et(3)N or, alternatively, by reacting [Co(PCP)(NO)](+) with b...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7842137/ https://www.ncbi.nlm.nih.gov/pubmed/33519014 http://dx.doi.org/10.1021/acs.organomet.0c00755 |