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Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes

[Image: see text] The synthesis, characterization, and catalytic activity of low-spin {CoNO}(8) pincer complexes of the type [Co(PCP)(NO)(H)] are described. These compounds are obtained either by reacting [Co(PCP)(κ(2)-BH(4))] with NO and Et(3)N or, alternatively, by reacting [Co(PCP)(NO)](+) with b...

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Detalles Bibliográficos
Autores principales: Pecak, Jan, Fleissner, Sarah, Veiros, Luis F., Pittenauer, Ernst, Stöger, Berthold, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7842137/
https://www.ncbi.nlm.nih.gov/pubmed/33519014
http://dx.doi.org/10.1021/acs.organomet.0c00755

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