Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylides to access chiral azabicycles

[2,3]-Sigmatropic rearrangement of ammonium ylides represents a fundamental reaction for stereoselective synthesis of nitrogenous compounds. However, its applicability is limited by the scarcity of efficient, catalytic, and mild methods for generating ammonium ylides. Here, we report silver-catalyze...

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Detalles Bibliográficos
Autores principales: Xi, Song, Dong, Jiawei, Chen, Haohua, Dong, Qiuyan, Yang, Jiao, Tan, Qiuyuan, Zhang, Changhui, Lan, Yu, Zhang, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7846163/
https://www.ncbi.nlm.nih.gov/pubmed/33514546
http://dx.doi.org/10.1126/sciadv.abd5290

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