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A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite
The simple ABO(3) and A-site-ordered AA′(3)B(4)O(12) perovskites represent two types of classical perovskite functional materials. There are well-known simple perovskites with ferroelectric properties, while there is still no report of ferroelectricity due to symmetry breaking transition in A-site-o...
| Autores principales: | , , , , , , , , , , , , , , , , , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7854592/ https://www.ncbi.nlm.nih.gov/pubmed/33531480 http://dx.doi.org/10.1038/s41467-020-20833-6 |
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| author | Zhao, Jianfa Gao, Jiacheng Li, Wenmin Qian, Yuting Shen, Xudong Wang, Xiao Shen, Xi Hu, Zhiwei Dong, Cheng Huang, Qingzhen Cao, Lipeng Li, Zhi Zhang, Jun Ren, Chongwen Duan, Lei Liu, Qingqing Yu, Richeng Ren, Yang Weng, Shih-Chang Lin, Hong-Ji Chen, Chien-Te Tjeng, Liu-Hao Long, Youwen Deng, Zheng Zhu, Jinlong Wang, Xiancheng Weng, Hongming Yu, Runze Greenblatt, Martha Jin, Changqing |
| author_facet | Zhao, Jianfa Gao, Jiacheng Li, Wenmin Qian, Yuting Shen, Xudong Wang, Xiao Shen, Xi Hu, Zhiwei Dong, Cheng Huang, Qingzhen Cao, Lipeng Li, Zhi Zhang, Jun Ren, Chongwen Duan, Lei Liu, Qingqing Yu, Richeng Ren, Yang Weng, Shih-Chang Lin, Hong-Ji Chen, Chien-Te Tjeng, Liu-Hao Long, Youwen Deng, Zheng Zhu, Jinlong Wang, Xiancheng Weng, Hongming Yu, Runze Greenblatt, Martha Jin, Changqing |
| author_sort | Zhao, Jianfa |
| collection | PubMed |
| description | The simple ABO(3) and A-site-ordered AA′(3)B(4)O(12) perovskites represent two types of classical perovskite functional materials. There are well-known simple perovskites with ferroelectric properties, while there is still no report of ferroelectricity due to symmetry breaking transition in A-site-ordered quadruple perovskites. Here we report the high pressure synthesis of an A-site-ordered perovskite PbHg(3)Ti(4)O(12), the only known quadruple perovskite that transforms from high-temperature centrosymmetric paraelectric phase to low-temperature non-centrosymmetric ferroelectric phase. The coordination chemistry of Hg(2+) is changed from square planar as in typical A-site-ordered quadruple perovskite to a rare stereo type with 8 ligands in PbHg(3)Ti(4)O(12). Thus PbHg(3)Ti(4)O(12) appears to be a combinatory link from simple ABO(3) perovskites to A-site-ordered AA′(3)Ti(4)O(12) perovskites, sharing both displacive ferroelectricity with former and structure coordination with latter. This is the only example so far showing ferroelectricity due to symmetry breaking phase transition in AA′(3)B(4)O(12)-type A-site-ordered perovskites, and opens a direction to search for ferroelectric materials. |
| format | Online Article Text |
| id | pubmed-7854592 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | Nature Publishing Group UK |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-78545922021-02-11 A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite Zhao, Jianfa Gao, Jiacheng Li, Wenmin Qian, Yuting Shen, Xudong Wang, Xiao Shen, Xi Hu, Zhiwei Dong, Cheng Huang, Qingzhen Cao, Lipeng Li, Zhi Zhang, Jun Ren, Chongwen Duan, Lei Liu, Qingqing Yu, Richeng Ren, Yang Weng, Shih-Chang Lin, Hong-Ji Chen, Chien-Te Tjeng, Liu-Hao Long, Youwen Deng, Zheng Zhu, Jinlong Wang, Xiancheng Weng, Hongming Yu, Runze Greenblatt, Martha Jin, Changqing Nat Commun Article The simple ABO(3) and A-site-ordered AA′(3)B(4)O(12) perovskites represent two types of classical perovskite functional materials. There are well-known simple perovskites with ferroelectric properties, while there is still no report of ferroelectricity due to symmetry breaking transition in A-site-ordered quadruple perovskites. Here we report the high pressure synthesis of an A-site-ordered perovskite PbHg(3)Ti(4)O(12), the only known quadruple perovskite that transforms from high-temperature centrosymmetric paraelectric phase to low-temperature non-centrosymmetric ferroelectric phase. The coordination chemistry of Hg(2+) is changed from square planar as in typical A-site-ordered quadruple perovskite to a rare stereo type with 8 ligands in PbHg(3)Ti(4)O(12). Thus PbHg(3)Ti(4)O(12) appears to be a combinatory link from simple ABO(3) perovskites to A-site-ordered AA′(3)Ti(4)O(12) perovskites, sharing both displacive ferroelectricity with former and structure coordination with latter. This is the only example so far showing ferroelectricity due to symmetry breaking phase transition in AA′(3)B(4)O(12)-type A-site-ordered perovskites, and opens a direction to search for ferroelectric materials. Nature Publishing Group UK 2021-02-02 /pmc/articles/PMC7854592/ /pubmed/33531480 http://dx.doi.org/10.1038/s41467-020-20833-6 Text en © The Author(s) 2021 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
| spellingShingle | Article Zhao, Jianfa Gao, Jiacheng Li, Wenmin Qian, Yuting Shen, Xudong Wang, Xiao Shen, Xi Hu, Zhiwei Dong, Cheng Huang, Qingzhen Cao, Lipeng Li, Zhi Zhang, Jun Ren, Chongwen Duan, Lei Liu, Qingqing Yu, Richeng Ren, Yang Weng, Shih-Chang Lin, Hong-Ji Chen, Chien-Te Tjeng, Liu-Hao Long, Youwen Deng, Zheng Zhu, Jinlong Wang, Xiancheng Weng, Hongming Yu, Runze Greenblatt, Martha Jin, Changqing A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite |
| title | A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite |
| title_full | A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite |
| title_fullStr | A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite |
| title_full_unstemmed | A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite |
| title_short | A combinatory ferroelectric compound bridging simple ABO(3) and A-site-ordered quadruple perovskite |
| title_sort | combinatory ferroelectric compound bridging simple abo(3) and a-site-ordered quadruple perovskite |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7854592/ https://www.ncbi.nlm.nih.gov/pubmed/33531480 http://dx.doi.org/10.1038/s41467-020-20833-6 |
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