Widening the Window of Spin-Crossover Temperatures in Bis(formazanate)iron(II) Complexes via Steric and Noncovalent Interactions

[Image: see text] Bis(formazanate)iron(II) complexes undergo a thermally induced S = 0 to S = 2 spin transition in solution. Here we present a study of how steric effects and π-stacking interactions between the triarylformazanate ligands affect the spin-crossover behavior, in addition to electronic...

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Detalles Bibliográficos
Autores principales: Milocco, Francesca, de Vries, Folkert, Siebe, Harmke S., Engbers, Silène, Demeshko, Serhiy, Meyer, Franc, Otten, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7856632/
https://www.ncbi.nlm.nih.gov/pubmed/33464882
http://dx.doi.org/10.1021/acs.inorgchem.0c03593

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7856632/
https://www.ncbi.nlm.nih.gov/pubmed/33464882
http://dx.doi.org/10.1021/acs.inorgchem.0c03593

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