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Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System

In recent years, the plasma gap resonance maintained by metal-film-coupled nanostructures has attracted extensive attention. This mainly originates from its flexible control of the spectral response and significantly enhanced field strength at the nanoparticle–film junction. In the present study, th...

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Autores principales: Yin, Yanping, Zhu, Jin, Wang, Zaoji, Ma, Guojun, Yuan, Huining, Li, Xiaolong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7859493/
https://www.ncbi.nlm.nih.gov/pubmed/33553101
http://dx.doi.org/10.3389/fchem.2020.553541
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author Yin, Yanping
Zhu, Jin
Wang, Zaoji
Ma, Guojun
Yuan, Huining
Li, Xiaolong
author_facet Yin, Yanping
Zhu, Jin
Wang, Zaoji
Ma, Guojun
Yuan, Huining
Li, Xiaolong
author_sort Yin, Yanping
collection PubMed
description In recent years, the plasma gap resonance maintained by metal-film-coupled nanostructures has attracted extensive attention. This mainly originates from its flexible control of the spectral response and significantly enhanced field strength at the nanoparticle–film junction. In the present study, the tunability of local surface plasmon resonances (LSPRs) of nanorods coupled to a gold film is studied theoretically. To this end, the plasmonic resonances in the nanostructure of individual silver nanorod–gold film (AgNR-film) with different parameters are investigated. Obtained results show that the refractive index sensitivity (S) of nanostructures to the environment increases as the aspect ratio (A(r)) of nanostructures increase. It is found that when the aspect ratio (A(r)) is set to 3.5, the figure of merit (FOM) is the highest. Moreover, the variation in the gap distances of the nanorod monomer–gold film, electric field distribution of nanorods dimer, and the corresponding impact on the gold film are studied. It is concluded that the gap size of nanostructures has an exponential correlation with the resonance wavelength. Considering the remarkable influence of the gap size and the surrounding medium environment on the spectral shift of AgNR-film nanostructures, potential applications of the structure as a refractive index sensor and biomolecule measurement are proposed.
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spelling pubmed-78594932021-02-05 Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System Yin, Yanping Zhu, Jin Wang, Zaoji Ma, Guojun Yuan, Huining Li, Xiaolong Front Chem Chemistry In recent years, the plasma gap resonance maintained by metal-film-coupled nanostructures has attracted extensive attention. This mainly originates from its flexible control of the spectral response and significantly enhanced field strength at the nanoparticle–film junction. In the present study, the tunability of local surface plasmon resonances (LSPRs) of nanorods coupled to a gold film is studied theoretically. To this end, the plasmonic resonances in the nanostructure of individual silver nanorod–gold film (AgNR-film) with different parameters are investigated. Obtained results show that the refractive index sensitivity (S) of nanostructures to the environment increases as the aspect ratio (A(r)) of nanostructures increase. It is found that when the aspect ratio (A(r)) is set to 3.5, the figure of merit (FOM) is the highest. Moreover, the variation in the gap distances of the nanorod monomer–gold film, electric field distribution of nanorods dimer, and the corresponding impact on the gold film are studied. It is concluded that the gap size of nanostructures has an exponential correlation with the resonance wavelength. Considering the remarkable influence of the gap size and the surrounding medium environment on the spectral shift of AgNR-film nanostructures, potential applications of the structure as a refractive index sensor and biomolecule measurement are proposed. Frontiers Media S.A. 2021-01-21 /pmc/articles/PMC7859493/ /pubmed/33553101 http://dx.doi.org/10.3389/fchem.2020.553541 Text en Copyright © 2021 Yin, Zhu, Wang, Ma, Yuan and Li. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Yin, Yanping
Zhu, Jin
Wang, Zaoji
Ma, Guojun
Yuan, Huining
Li, Xiaolong
Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System
title Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System
title_full Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System
title_fullStr Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System
title_full_unstemmed Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System
title_short Enhanced Plasmonic Resonance Characteristics of AgNRs–Gold Film Hybrid System
title_sort enhanced plasmonic resonance characteristics of agnrs–gold film hybrid system
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7859493/
https://www.ncbi.nlm.nih.gov/pubmed/33553101
http://dx.doi.org/10.3389/fchem.2020.553541
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