Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene

Perfluorinated tetrathiacalix[4]arene was obtained by heating perfluoro-m-xylene with thiourea or 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol at 90 °C. Interaction of perfluoro-m-xylene with resorcinol or orcinol under mild conditions and subsequent heating of the mixture with 2,5-diflu...

Descripción completa

Detalles Bibliográficos
Autores principales: Kovtonyuk, Vladimir N., Gatilov, Yuri V., Nikul’shin, Pavel V., Bredikhin, Roman A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7864041/
https://www.ncbi.nlm.nih.gov/pubmed/33498335
http://dx.doi.org/10.3390/molecules26030526
_version_ 1783647593663823872
author Kovtonyuk, Vladimir N.
Gatilov, Yuri V.
Nikul’shin, Pavel V.
Bredikhin, Roman A.
author_facet Kovtonyuk, Vladimir N.
Gatilov, Yuri V.
Nikul’shin, Pavel V.
Bredikhin, Roman A.
author_sort Kovtonyuk, Vladimir N.
collection PubMed
description Perfluorinated tetrathiacalix[4]arene was obtained by heating perfluoro-m-xylene with thiourea or 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol at 90 °C. Interaction of perfluoro-m-xylene with resorcinol or orcinol under mild conditions and subsequent heating of the mixture with 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol leads to polyfluorinated dioxadithiacalix[4]arenes. Triphenyl and pentaphenyl ethers formed by the interaction of perfluoro-m-xylene with resorcinol under heating with thiourea gives polyfluorinated oxathiacalixarenes containing six and five aromatic nuclei, respectively.
format Online
Article
Text
id pubmed-7864041
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-78640412021-02-06 Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene Kovtonyuk, Vladimir N. Gatilov, Yuri V. Nikul’shin, Pavel V. Bredikhin, Roman A. Molecules Article Perfluorinated tetrathiacalix[4]arene was obtained by heating perfluoro-m-xylene with thiourea or 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol at 90 °C. Interaction of perfluoro-m-xylene with resorcinol or orcinol under mild conditions and subsequent heating of the mixture with 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol leads to polyfluorinated dioxadithiacalix[4]arenes. Triphenyl and pentaphenyl ethers formed by the interaction of perfluoro-m-xylene with resorcinol under heating with thiourea gives polyfluorinated oxathiacalixarenes containing six and five aromatic nuclei, respectively. MDPI 2021-01-20 /pmc/articles/PMC7864041/ /pubmed/33498335 http://dx.doi.org/10.3390/molecules26030526 Text en © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kovtonyuk, Vladimir N.
Gatilov, Yuri V.
Nikul’shin, Pavel V.
Bredikhin, Roman A.
Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
title Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
title_full Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
title_fullStr Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
title_full_unstemmed Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
title_short Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
title_sort synthesis of polyfluorinated thia- and oxathiacalixarenes based on perfluoro-m-xylene
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7864041/
https://www.ncbi.nlm.nih.gov/pubmed/33498335
http://dx.doi.org/10.3390/molecules26030526
work_keys_str_mv AT kovtonyukvladimirn synthesisofpolyfluorinatedthiaandoxathiacalixarenesbasedonperfluoromxylene
AT gatilovyuriv synthesisofpolyfluorinatedthiaandoxathiacalixarenesbasedonperfluoromxylene
AT nikulshinpavelv synthesisofpolyfluorinatedthiaandoxathiacalixarenesbasedonperfluoromxylene
AT bredikhinromana synthesisofpolyfluorinatedthiaandoxathiacalixarenesbasedonperfluoromxylene

Ejemplares similares