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N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate
The title compound, C(30)H(39)N(3)·0.5C(7)H(8), is a symmetrically N,N′-disubstituted arylamidine containing a 4-pyridyl substituent on the carbon atom of the N–C–N linkage and bulky 2,6-diisopropylphenyl groups on the nitrogen atoms. It crystallizes in the Z-anti configuration and its amidine C...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7869534/ https://www.ncbi.nlm.nih.gov/pubmed/33614137 http://dx.doi.org/10.1107/S2056989021000141 |
| _version_ | 1783648647757430784 |
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| author | Cottin, Lola Girard, Sarah Hanan, Garry S. Cibian, Mihaela |
| author_facet | Cottin, Lola Girard, Sarah Hanan, Garry S. Cibian, Mihaela |
| author_sort | Cottin, Lola |
| collection | PubMed |
| description | The title compound, C(30)H(39)N(3)·0.5C(7)H(8), is a symmetrically N,N′-disubstituted arylamidine containing a 4-pyridyl substituent on the carbon atom of the N–C–N linkage and bulky 2,6-diisopropylphenyl groups on the nitrogen atoms. It crystallizes in the Z-anti configuration and its amidine C—N bonds present amine [1.368 (1) Å] and imine [1.286 (1) Å] features. Intramolecular hydrogen bonds are present in the structure together with intermolecular N—H⋯N and C—H⋯N interactions linking the molecules in chains along the a- and c-axis directions. |
| format | Online Article Text |
| id | pubmed-7869534 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-78695342021-02-19 N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate Cottin, Lola Girard, Sarah Hanan, Garry S. Cibian, Mihaela Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(30)H(39)N(3)·0.5C(7)H(8), is a symmetrically N,N′-disubstituted arylamidine containing a 4-pyridyl substituent on the carbon atom of the N–C–N linkage and bulky 2,6-diisopropylphenyl groups on the nitrogen atoms. It crystallizes in the Z-anti configuration and its amidine C—N bonds present amine [1.368 (1) Å] and imine [1.286 (1) Å] features. Intramolecular hydrogen bonds are present in the structure together with intermolecular N—H⋯N and C—H⋯N interactions linking the molecules in chains along the a- and c-axis directions. International Union of Crystallography 2021-01-12 /pmc/articles/PMC7869534/ /pubmed/33614137 http://dx.doi.org/10.1107/S2056989021000141 Text en © Cottin et al. 2021 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Cottin, Lola Girard, Sarah Hanan, Garry S. Cibian, Mihaela N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| title |
N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| title_full |
N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| title_fullStr |
N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| title_full_unstemmed |
N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| title_short |
N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| title_sort | n,n′-bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7869534/ https://www.ncbi.nlm.nih.gov/pubmed/33614137 http://dx.doi.org/10.1107/S2056989021000141 |
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