Stimuli-Responsive Internally Ion-Paired Supramolecular Polymer Based on a Bis-pillar[5]arene Dicarboxylic Acid Monomer

[Image: see text] A novel bis-pillar[5]arene dicarboxylic acid self-assembles in the presence of 1,12-diaminododecane to yield overall neutral, internally ion-paired supramolecular polymers. Their aggregation, binding mode, and morphology can be tuned by external stimuli such as solvent polarity, co...

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Detalles Bibliográficos
Autores principales: Notti, Anna, Pisagatti, Ilenia, Nastasi, Francesco, Patanè, Salvatore, Parisi, Melchiorre F., Gattuso, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7871325/
https://www.ncbi.nlm.nih.gov/pubmed/33369427
http://dx.doi.org/10.1021/acs.joc.0c02501
Descripción
Sumario:[Image: see text] A novel bis-pillar[5]arene dicarboxylic acid self-assembles in the presence of 1,12-diaminododecane to yield overall neutral, internally ion-paired supramolecular polymers. Their aggregation, binding mode, and morphology can be tuned by external stimuli such as solvent polarity, concentration, and base treatment.

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