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Tricyclo[2.1.0.0(2,5)]pent-3-ylidene: Stereoelectronic Control of Bridge-Flapping within a Nonclassical Nucleophilic Carbene
[Image: see text] Tricyclo[2.1.0.0(2,5)]pent-3-ylidene is a carbene foreseen to rearrange to pyramidane (c-C(4)H(4))C, a highly strained molecule featuring an inverted C atom. Modeling of the carbene, using the (U)MPWB1K/cc-pVTZ//(U)MPWB1K/6-311G(d) theoretical model, indicated a large singlet–tripl...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7872432/ https://www.ncbi.nlm.nih.gov/pubmed/33355456 http://dx.doi.org/10.1021/acs.joc.0c02414 |