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Chalcogenido‐Dimethylgallates and ‐Indates DMPyr(2)[Me(2)M(μ(2)−E)](2) (M=Ga, In; E=S, Se): Building Blocks for Higher and Lower Order Chalcogenidoindates

Metalation of the anions in the ionic liquids DMPyr[SH] and DMPyr[SeH] (DMPyr=1,1‐dimethylpyrrolidinium) by trimethylgallium and trimethylindium is investigated. The reaction proceeds via pre‐coordination of [EH](−), methane elimination and formation of an unprecedented series of chalcogenido metala...

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Detalles Bibliográficos
Autores principales: Guschlbauer, Jannick, Vollgraff, Tobias, Finger, Lars H., Harms, Klaus, Sundermeyer, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7874246/
https://www.ncbi.nlm.nih.gov/pubmed/33565735
http://dx.doi.org/10.1002/open.202000347