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Chalcogenido‐Dimethylgallates and ‐Indates DMPyr(2)[Me(2)M(μ(2)−E)](2) (M=Ga, In; E=S, Se): Building Blocks for Higher and Lower Order Chalcogenidoindates
Metalation of the anions in the ionic liquids DMPyr[SH] and DMPyr[SeH] (DMPyr=1,1‐dimethylpyrrolidinium) by trimethylgallium and trimethylindium is investigated. The reaction proceeds via pre‐coordination of [EH](−), methane elimination and formation of an unprecedented series of chalcogenido metala...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7874246/ https://www.ncbi.nlm.nih.gov/pubmed/33565735 http://dx.doi.org/10.1002/open.202000347 |