Volatility of molten salts [Ph(4)P][NTf(2)] and Cs[NTf(2)]

The two ionic compounds [Ph(4)P][NTf(2)] and Cs[NTf(2)] were qualified to be suitable liquid materials for different high temperature applications. Development and optimization of these application techniques require knowledge of the thermodynamic properties of vaporization. Vapor pressures and vapo...

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Detalles Bibliográficos
Autores principales: Zaitsau, Dzmitry H., Gantman, Mikhail, Schulz, Peter, Wasserscheid, Peter, Verevkin, Sergey P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7874263/
http://dx.doi.org/10.1002/open.202000260
Descripción
Sumario:The two ionic compounds [Ph(4)P][NTf(2)] and Cs[NTf(2)] were qualified to be suitable liquid materials for different high temperature applications. Development and optimization of these application techniques require knowledge of the thermodynamic properties of vaporization. Vapor pressures and vaporization enthalpies have been measured by using quartz‐crystal microbalance. Solubility parameters and miscibility of ionic liquids in practically relevant solvents were assessed.

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