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Intermolecular π–π Stacking Interactions Made Visible

[Image: see text] Mixing the liquids hexafluorobenzene (1) and 1,3,5-trimethylbenzene (mesitylene, 2) results in a crystalline solid with a melting point of 34 °C. The solid consists of alternating π–π stacked pillars of both aromatics. This simple experiment can be used to visually demonstrate the...

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Detalles Bibliográficos
Autores principales: Timmer, Brian Jacobus Jozefus, Mooibroek, Tiddo Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society and Division of Chemical Education, Inc. 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7876799/
https://www.ncbi.nlm.nih.gov/pubmed/33583952
http://dx.doi.org/10.1021/acs.jchemed.0c01252