Cargando…
Microsecond Photoluminescence and Photoreactivity of a Metal-Centered Excited State in a Hexacarbene–Co(III) Complex
[Image: see text] The photofunctionality of the cobalt–hexacarbene complex [Co(III)(PhB(MeIm)(3))(2)](+) (PhB(MeIm)(3) = tris(3-methylimidazolin-2-ylidene)(phenyl)borate) has been investigated by time-resolved optical spectroscopy. The complex displays a weak (Φ ∼ 10(–4)) but remarkably long-lived (...
| Autores principales: | , , , , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2021
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7877722/ https://www.ncbi.nlm.nih.gov/pubmed/33449685 http://dx.doi.org/10.1021/jacs.0c12151 |