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Cage Adaption by High-Pressure Synthesis: The Clathrate-I Borosilicide Rb(8)B(8)Si(38)
[Image: see text] Rb(8)B(8)Si(38) forms under high-pressure, high-temperature conditions at p = 8 GPa and T = 1273 K. The new compound (space group Pm3̅n, a = 9.9583(1) Å) is the second example for a clathrate-I borosilicide. The phase is inert against strong acids and bases and thermally stable up...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7887739/ https://www.ncbi.nlm.nih.gov/pubmed/33104343 http://dx.doi.org/10.1021/acs.inorgchem.0c02357 |
| _version_ | 1783652040585510912 |
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| author | Hübner, Julia-Maria Jung, Walter Schmidt, Marcus Bobnar, Matej Koželj, Primož Böhme, Bodo Baitinger, Michael Etter, Martin Grin, Yuri Schwarz, Ulrich |
| author_facet | Hübner, Julia-Maria Jung, Walter Schmidt, Marcus Bobnar, Matej Koželj, Primož Böhme, Bodo Baitinger, Michael Etter, Martin Grin, Yuri Schwarz, Ulrich |
| author_sort | Hübner, Julia-Maria |
| collection | PubMed |
| description | [Image: see text] Rb(8)B(8)Si(38) forms under high-pressure, high-temperature conditions at p = 8 GPa and T = 1273 K. The new compound (space group Pm3̅n, a = 9.9583(1) Å) is the second example for a clathrate-I borosilicide. The phase is inert against strong acids and bases and thermally stable up to 1300 K at ambient pressure. (Rb(+))(8)(B(–))(8)(Si(0))(38) is electronically balanced, diamagnetic, and shows semiconducting behavior with moderate Seebeck coefficient below 300 K. Chemical bonding analysis by the electron localizability approach confirms the description of Rb(8)B(8)Si(38) as Zintl phase. |
| format | Online Article Text |
| id | pubmed-7887739 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | American
Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-78877392021-02-17 Cage Adaption by High-Pressure Synthesis: The Clathrate-I Borosilicide Rb(8)B(8)Si(38) Hübner, Julia-Maria Jung, Walter Schmidt, Marcus Bobnar, Matej Koželj, Primož Böhme, Bodo Baitinger, Michael Etter, Martin Grin, Yuri Schwarz, Ulrich Inorg Chem [Image: see text] Rb(8)B(8)Si(38) forms under high-pressure, high-temperature conditions at p = 8 GPa and T = 1273 K. The new compound (space group Pm3̅n, a = 9.9583(1) Å) is the second example for a clathrate-I borosilicide. The phase is inert against strong acids and bases and thermally stable up to 1300 K at ambient pressure. (Rb(+))(8)(B(–))(8)(Si(0))(38) is electronically balanced, diamagnetic, and shows semiconducting behavior with moderate Seebeck coefficient below 300 K. Chemical bonding analysis by the electron localizability approach confirms the description of Rb(8)B(8)Si(38) as Zintl phase. American Chemical Society 2020-10-26 2021-02-15 /pmc/articles/PMC7887739/ /pubmed/33104343 http://dx.doi.org/10.1021/acs.inorgchem.0c02357 Text en © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. |
| spellingShingle | Hübner, Julia-Maria Jung, Walter Schmidt, Marcus Bobnar, Matej Koželj, Primož Böhme, Bodo Baitinger, Michael Etter, Martin Grin, Yuri Schwarz, Ulrich Cage Adaption by High-Pressure Synthesis: The Clathrate-I Borosilicide Rb(8)B(8)Si(38) |
| title | Cage Adaption by High-Pressure Synthesis: The Clathrate-I
Borosilicide Rb(8)B(8)Si(38) |
| title_full | Cage Adaption by High-Pressure Synthesis: The Clathrate-I
Borosilicide Rb(8)B(8)Si(38) |
| title_fullStr | Cage Adaption by High-Pressure Synthesis: The Clathrate-I
Borosilicide Rb(8)B(8)Si(38) |
| title_full_unstemmed | Cage Adaption by High-Pressure Synthesis: The Clathrate-I
Borosilicide Rb(8)B(8)Si(38) |
| title_short | Cage Adaption by High-Pressure Synthesis: The Clathrate-I
Borosilicide Rb(8)B(8)Si(38) |
| title_sort | cage adaption by high-pressure synthesis: the clathrate-i
borosilicide rb(8)b(8)si(38) |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7887739/ https://www.ncbi.nlm.nih.gov/pubmed/33104343 http://dx.doi.org/10.1021/acs.inorgchem.0c02357 |
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