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Cage Adaption by High-Pressure Synthesis: The Clathrate-I Borosilicide Rb(8)B(8)Si(38)
[Image: see text] Rb(8)B(8)Si(38) forms under high-pressure, high-temperature conditions at p = 8 GPa and T = 1273 K. The new compound (space group Pm3̅n, a = 9.9583(1) Å) is the second example for a clathrate-I borosilicide. The phase is inert against strong acids and bases and thermally stable up...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7887739/ https://www.ncbi.nlm.nih.gov/pubmed/33104343 http://dx.doi.org/10.1021/acs.inorgchem.0c02357 |