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Green Thermoplastic Vulcanizates Based on Silicone Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization
[Image: see text] Presenting a combination of sustainability and environmental friendliness, a new class of green and non-petroleum-based thermoplastic vulcanizates (TPVs) was successfully developed from silica-filled silicone rubber (FSR) and poly(butylene succinate) (PBS) via dynamic vulcanization...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7893803/ https://www.ncbi.nlm.nih.gov/pubmed/33623852 http://dx.doi.org/10.1021/acsomega.0c06036 |
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author | Liang, Yufeng Wang, Haoyu Li, Jiahuan Wu, Shaowei Han, Wenchi Kang, Hailan Fang, Qinghong |
author_facet | Liang, Yufeng Wang, Haoyu Li, Jiahuan Wu, Shaowei Han, Wenchi Kang, Hailan Fang, Qinghong |
author_sort | Liang, Yufeng |
collection | PubMed |
description | [Image: see text] Presenting a combination of sustainability and environmental friendliness, a new class of green and non-petroleum-based thermoplastic vulcanizates (TPVs) was successfully developed from silica-filled silicone rubber (FSR) and poly(butylene succinate) (PBS) via dynamic vulcanization. The phase morphology, interfacial compatibilization, and microstructural properties of FSR/PBS TPVs were investigated. Notably, a large number of FSR microparticles were observed and were dispersed in the continuous PBS phase, indicating complete phase inversion during the dynamic vulcanization. The fine phase morphology of FSR/PBS TPVs was achieved by a fine phase morphology of the SR/PBS premix, the good interfacial compatibility between the PBS phase and the cross-linked FSR phase, and complete phase inversion. The as-prepared TPVs possessed high tensile strength, good elastic behavior, easy processability, and reprocessability. These novel non-petroleum-based TPVs have potential applications in packagings, biomedical devices, and three-dimensional (3D) printing materials. |
format | Online Article Text |
id | pubmed-7893803 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-78938032021-02-22 Green Thermoplastic Vulcanizates Based on Silicone Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization Liang, Yufeng Wang, Haoyu Li, Jiahuan Wu, Shaowei Han, Wenchi Kang, Hailan Fang, Qinghong ACS Omega [Image: see text] Presenting a combination of sustainability and environmental friendliness, a new class of green and non-petroleum-based thermoplastic vulcanizates (TPVs) was successfully developed from silica-filled silicone rubber (FSR) and poly(butylene succinate) (PBS) via dynamic vulcanization. The phase morphology, interfacial compatibilization, and microstructural properties of FSR/PBS TPVs were investigated. Notably, a large number of FSR microparticles were observed and were dispersed in the continuous PBS phase, indicating complete phase inversion during the dynamic vulcanization. The fine phase morphology of FSR/PBS TPVs was achieved by a fine phase morphology of the SR/PBS premix, the good interfacial compatibility between the PBS phase and the cross-linked FSR phase, and complete phase inversion. The as-prepared TPVs possessed high tensile strength, good elastic behavior, easy processability, and reprocessability. These novel non-petroleum-based TPVs have potential applications in packagings, biomedical devices, and three-dimensional (3D) printing materials. American Chemical Society 2021-02-02 /pmc/articles/PMC7893803/ /pubmed/33623852 http://dx.doi.org/10.1021/acsomega.0c06036 Text en © 2021 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. |
spellingShingle | Liang, Yufeng Wang, Haoyu Li, Jiahuan Wu, Shaowei Han, Wenchi Kang, Hailan Fang, Qinghong Green Thermoplastic Vulcanizates Based on Silicone Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization |
title | Green Thermoplastic Vulcanizates Based on Silicone
Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization |
title_full | Green Thermoplastic Vulcanizates Based on Silicone
Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization |
title_fullStr | Green Thermoplastic Vulcanizates Based on Silicone
Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization |
title_full_unstemmed | Green Thermoplastic Vulcanizates Based on Silicone
Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization |
title_short | Green Thermoplastic Vulcanizates Based on Silicone
Rubber and Poly(butylene succinate) via In Situ Interfacial Compatibilization |
title_sort | green thermoplastic vulcanizates based on silicone
rubber and poly(butylene succinate) via in situ interfacial compatibilization |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7893803/ https://www.ncbi.nlm.nih.gov/pubmed/33623852 http://dx.doi.org/10.1021/acsomega.0c06036 |
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