Main‐Group Metallocenophanes

Metallocenes with interlinked cyclopentadienide ligands are commonly referred to as ansa‐metallocenes or metallocenophanes. These can have drastically different properties than their unbridged parent compounds. While this concept is best known for transition metals such as iron, it can also be adopt...

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Detalles Bibliográficos
Autores principales: Wirtz, Lisa, Schäfer, André
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Reviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894164/
https://www.ncbi.nlm.nih.gov/pubmed/32735356
http://dx.doi.org/10.1002/chem.202003161
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author Wirtz, Lisa
Schäfer, André
author_facet Wirtz, Lisa
Schäfer, André
author_sort Wirtz, Lisa
collection PubMed
description Metallocenes with interlinked cyclopentadienide ligands are commonly referred to as ansa‐metallocenes or metallocenophanes. These can have drastically different properties than their unbridged parent compounds. While this concept is best known for transition metals such as iron, it can also be adopted for many main‐group elements. This review aims to summarize recent advances in the field of metallocenophanes based on main‐group elements of group 2, group 13, group 14 and group 15, focusing on synthesis, structure and properties of these compounds.
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spelling pubmed-78941642021-03-02 Main‐Group Metallocenophanes Wirtz, Lisa Schäfer, André Chemistry Reviews Metallocenes with interlinked cyclopentadienide ligands are commonly referred to as ansa‐metallocenes or metallocenophanes. These can have drastically different properties than their unbridged parent compounds. While this concept is best known for transition metals such as iron, it can also be adopted for many main‐group elements. This review aims to summarize recent advances in the field of metallocenophanes based on main‐group elements of group 2, group 13, group 14 and group 15, focusing on synthesis, structure and properties of these compounds. John Wiley and Sons Inc. 2020-10-28 2021-01-18 /pmc/articles/PMC7894164/ /pubmed/32735356 http://dx.doi.org/10.1002/chem.202003161 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Reviews
Wirtz, Lisa
Schäfer, André
Main‐Group Metallocenophanes
title Main‐Group Metallocenophanes
title_full Main‐Group Metallocenophanes
title_fullStr Main‐Group Metallocenophanes
title_full_unstemmed Main‐Group Metallocenophanes
title_short Main‐Group Metallocenophanes
title_sort main‐group metallocenophanes
topic Reviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894164/
https://www.ncbi.nlm.nih.gov/pubmed/32735356
http://dx.doi.org/10.1002/chem.202003161
work_keys_str_mv AT wirtzlisa maingroupmetallocenophanes
AT schaferandre maingroupmetallocenophanes

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