Reversible Reductive Elimination in Aluminum(II) Dihydrides

Oxidative addition and reductive elimination are defining reactions of transition‐metal organometallic chemistry. In main‐group chemistry, oxidative addition is now well‐established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported b...

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Detalles Bibliográficos
Autores principales: Falconer, Rosalyn L., Nichol, Gary S., Smolyar, Ivan V., Cockroft, Scott L., Cowley, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894477/
https://www.ncbi.nlm.nih.gov/pubmed/33022874
http://dx.doi.org/10.1002/anie.202011418
Descripción
Sumario:Oxidative addition and reductive elimination are defining reactions of transition‐metal organometallic chemistry. In main‐group chemistry, oxidative addition is now well‐established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al(I) and Al(III) intermediates.

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