Reversible Reductive Elimination in Aluminum(II) Dihydrides

Oxidative addition and reductive elimination are defining reactions of transition‐metal organometallic chemistry. In main‐group chemistry, oxidative addition is now well‐established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported b...

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Detalles Bibliográficos
Autores principales: Falconer, Rosalyn L., Nichol, Gary S., Smolyar, Ivan V., Cockroft, Scott L., Cowley, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894477/
https://www.ncbi.nlm.nih.gov/pubmed/33022874
http://dx.doi.org/10.1002/anie.202011418
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author Falconer, Rosalyn L.
Nichol, Gary S.
Smolyar, Ivan V.
Cockroft, Scott L.
Cowley, Michael J.
author_facet Falconer, Rosalyn L.
Nichol, Gary S.
Smolyar, Ivan V.
Cockroft, Scott L.
Cowley, Michael J.
author_sort Falconer, Rosalyn L.
collection PubMed
description Oxidative addition and reductive elimination are defining reactions of transition‐metal organometallic chemistry. In main‐group chemistry, oxidative addition is now well‐established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al(I) and Al(III) intermediates.
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spelling pubmed-78944772021-03-02 Reversible Reductive Elimination in Aluminum(II) Dihydrides Falconer, Rosalyn L. Nichol, Gary S. Smolyar, Ivan V. Cockroft, Scott L. Cowley, Michael J. Angew Chem Int Ed Engl Communications Oxidative addition and reductive elimination are defining reactions of transition‐metal organometallic chemistry. In main‐group chemistry, oxidative addition is now well‐established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al(I) and Al(III) intermediates. John Wiley and Sons Inc. 2020-11-24 2021-01-25 /pmc/articles/PMC7894477/ /pubmed/33022874 http://dx.doi.org/10.1002/anie.202011418 Text en © 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Falconer, Rosalyn L.
Nichol, Gary S.
Smolyar, Ivan V.
Cockroft, Scott L.
Cowley, Michael J.
Reversible Reductive Elimination in Aluminum(II) Dihydrides
title Reversible Reductive Elimination in Aluminum(II) Dihydrides
title_full Reversible Reductive Elimination in Aluminum(II) Dihydrides
title_fullStr Reversible Reductive Elimination in Aluminum(II) Dihydrides
title_full_unstemmed Reversible Reductive Elimination in Aluminum(II) Dihydrides
title_short Reversible Reductive Elimination in Aluminum(II) Dihydrides
title_sort reversible reductive elimination in aluminum(ii) dihydrides
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894477/
https://www.ncbi.nlm.nih.gov/pubmed/33022874
http://dx.doi.org/10.1002/anie.202011418
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AT cockroftscottl reversiblereductiveeliminationinaluminumiidihydrides
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