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Selective Transformation of Nickel‐Bound Formate to CO or C−C Coupling Products Triggered by Deprotonation and Steered by Alkali‐Metal Ions

The complexes [L(tBu)Ni(OCO‐κ (2) O,C)]M(3)[N(SiMe(3))(2)](2) (M=Li, Na, K), synthesized by deprotonation of a nickel formate complex [L(tBu)NiOOCH] with the corresponding amides M[N(SiMe(3))(2)], feature a Ni(II)−CO(2) (2−) core surrounded by Lewis‐acidic cations (M(+)) and the influence of the lat...

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Detalles Bibliográficos
Autores principales:	Zimmermann, Philipp, Ar, Deniz, Rößler, Marie, Holze, Patrick, Cula, Beatrice, Herwig, Christian, Limberg, Christian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898393/ https://www.ncbi.nlm.nih.gov/pubmed/33084156 http://dx.doi.org/10.1002/anie.202010180

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