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Unsupported Mg–Alkene Bonding

The first intermolecular early main group metal–alkene complexes were isolated. This was enabled by using highly Lewis acidic Mg centers in the Lewis base‐free cations ((Me)BDI)Mg(+) and ((tBu)BDI)Mg(+) with B(C(6)F(5))(4) (−) counterions ((Me)BDI=CH[C(CH(3))N(DIPP)](2), (tBu)BDI=CH[C(tBu)N(DIPP)](2...

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Detalles Bibliográficos
Autores principales:	Thum, Katharina, Friedrich, Alexander, Pahl, Jürgen, Elsen, Holger, Langer, Jens, Harder, Sjoerd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898539/ https://www.ncbi.nlm.nih.gov/pubmed/33197075 http://dx.doi.org/10.1002/chem.202004716

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